cis-(1,4,8,11-Tetra­aza­cyclo­tetra­decane-κN (4))bis(­thio­cyanato-κN)chromium(III) thio­cyanate

The crystal structure of [Cr(NCS)(2)(cyclam)]NCS (cyclam = 1,4,8,11-tetra­aza­cyclo­tetra­deca­ne, C(10)H(24)N(4)) has been determined by using synchrotron radiation at 98 K. The Cr(III) atom is in a slightly distorted octa­hedral environment with four N atoms of the macrocyclic ligand and two N-coo...

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Autores principales: Moon, Dohyun, Choi, Jong-Ha, Ryoo, Keon Sang, Hong, Yong Pyo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772415/
https://www.ncbi.nlm.nih.gov/pubmed/24046558
http://dx.doi.org/10.1107/S1600536813015456
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author Moon, Dohyun
Choi, Jong-Ha
Ryoo, Keon Sang
Hong, Yong Pyo
author_facet Moon, Dohyun
Choi, Jong-Ha
Ryoo, Keon Sang
Hong, Yong Pyo
author_sort Moon, Dohyun
collection PubMed
description The crystal structure of [Cr(NCS)(2)(cyclam)]NCS (cyclam = 1,4,8,11-tetra­aza­cyclo­tetra­deca­ne, C(10)H(24)N(4)) has been determined by using synchrotron radiation at 98 K. The Cr(III) atom is in a slightly distorted octa­hedral environment with four N atoms of the macrocyclic ligand and two N-coordinated NCS(−) anions in cis positions. The average Cr—N(cyclam) and Cr—NCS bond lengths are 2.085 (5) and 1.996 (15) Å, respectively. In the crystal, the uncoordinating SCN(−) anion is hydrogen bonded through N—H⋯S and N—H⋯N inter­actions to neighbouring complex cations.
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spelling pubmed-37724152013-09-17 cis-(1,4,8,11-Tetra­aza­cyclo­tetra­decane-κN (4))bis(­thio­cyanato-κN)chromium(III) thio­cyanate Moon, Dohyun Choi, Jong-Ha Ryoo, Keon Sang Hong, Yong Pyo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of [Cr(NCS)(2)(cyclam)]NCS (cyclam = 1,4,8,11-tetra­aza­cyclo­tetra­deca­ne, C(10)H(24)N(4)) has been determined by using synchrotron radiation at 98 K. The Cr(III) atom is in a slightly distorted octa­hedral environment with four N atoms of the macrocyclic ligand and two N-coordinated NCS(−) anions in cis positions. The average Cr—N(cyclam) and Cr—NCS bond lengths are 2.085 (5) and 1.996 (15) Å, respectively. In the crystal, the uncoordinating SCN(−) anion is hydrogen bonded through N—H⋯S and N—H⋯N inter­actions to neighbouring complex cations. International Union of Crystallography 2013-06-12 /pmc/articles/PMC3772415/ /pubmed/24046558 http://dx.doi.org/10.1107/S1600536813015456 Text en © Moon et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Moon, Dohyun
Choi, Jong-Ha
Ryoo, Keon Sang
Hong, Yong Pyo
cis-(1,4,8,11-Tetra­aza­cyclo­tetra­decane-κN (4))bis(­thio­cyanato-κN)chromium(III) thio­cyanate
title cis-(1,4,8,11-Tetra­aza­cyclo­tetra­decane-κN (4))bis(­thio­cyanato-κN)chromium(III) thio­cyanate
title_full cis-(1,4,8,11-Tetra­aza­cyclo­tetra­decane-κN (4))bis(­thio­cyanato-κN)chromium(III) thio­cyanate
title_fullStr cis-(1,4,8,11-Tetra­aza­cyclo­tetra­decane-κN (4))bis(­thio­cyanato-κN)chromium(III) thio­cyanate
title_full_unstemmed cis-(1,4,8,11-Tetra­aza­cyclo­tetra­decane-κN (4))bis(­thio­cyanato-κN)chromium(III) thio­cyanate
title_short cis-(1,4,8,11-Tetra­aza­cyclo­tetra­decane-κN (4))bis(­thio­cyanato-κN)chromium(III) thio­cyanate
title_sort cis-(1,4,8,11-tetra­aza­cyclo­tetra­decane-κn (4))bis(­thio­cyanato-κn)chromium(iii) thio­cyanate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772415/
https://www.ncbi.nlm.nih.gov/pubmed/24046558
http://dx.doi.org/10.1107/S1600536813015456
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AT choijongha cis14811tetraazacyclotetradecanekn4bisthiocyanatoknchromiumiiithiocyanate
AT ryookeonsang cis14811tetraazacyclotetradecanekn4bisthiocyanatoknchromiumiiithiocyanate
AT hongyongpyo cis14811tetraazacyclotetradecanekn4bisthiocyanatoknchromiumiiithiocyanate

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