4-(Di­methyl­amino)­pyridinium trichlorido[4-(di­methyl­amino)­pyridine-κN]cobaltate(II)

In the anion of the title compound, (C(7)H(11)N(2))[CoCl(3)(C(7)H(10)N(2))], the Co(II) ion is coordinated by one N atom from a 4-(di­methyl­amino)­pyridine (DMAP) ligand and three Cl atoms, forming a CoNCl(3) polyhedron with a distorted tetra­hedral geometry. In the crystal, cations and anions are...

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Detalles Bibliográficos
Autores principales: Guenifa, Fatiha, Hadjadj, Nasreddine, Zeghouan, Ouahida, Bendjeddou, Lamia, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772417/
https://www.ncbi.nlm.nih.gov/pubmed/24046560
http://dx.doi.org/10.1107/S1600536813015602
Descripción
Sumario:In the anion of the title compound, (C(7)H(11)N(2))[CoCl(3)(C(7)H(10)N(2))], the Co(II) ion is coordinated by one N atom from a 4-(di­methyl­amino)­pyridine (DMAP) ligand and three Cl atoms, forming a CoNCl(3) polyhedron with a distorted tetra­hedral geometry. In the crystal, cations and anions are linked via weak N—H⋯Cl and C—H⋯Cl hydrogen bonds. Double layers of complex anions stack along the b- axis direction, which alternate with double layers of 4-(di­methyl­amino)-pyridinium cations.

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