4-(Di­methyl­amino)­pyridinium trichlorido[4-(di­methyl­amino)­pyridine-κN]cobaltate(II)

In the anion of the title compound, (C(7)H(11)N(2))[CoCl(3)(C(7)H(10)N(2))], the Co(II) ion is coordinated by one N atom from a 4-(di­methyl­amino)­pyridine (DMAP) ligand and three Cl atoms, forming a CoNCl(3) polyhedron with a distorted tetra­hedral geometry. In the crystal, cations and anions are...

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Autores principales: Guenifa, Fatiha, Hadjadj, Nasreddine, Zeghouan, Ouahida, Bendjeddou, Lamia, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772417/
https://www.ncbi.nlm.nih.gov/pubmed/24046560
http://dx.doi.org/10.1107/S1600536813015602
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author Guenifa, Fatiha
Hadjadj, Nasreddine
Zeghouan, Ouahida
Bendjeddou, Lamia
Merazig, Hocine
author_facet Guenifa, Fatiha
Hadjadj, Nasreddine
Zeghouan, Ouahida
Bendjeddou, Lamia
Merazig, Hocine
author_sort Guenifa, Fatiha
collection PubMed
description In the anion of the title compound, (C(7)H(11)N(2))[CoCl(3)(C(7)H(10)N(2))], the Co(II) ion is coordinated by one N atom from a 4-(di­methyl­amino)­pyridine (DMAP) ligand and three Cl atoms, forming a CoNCl(3) polyhedron with a distorted tetra­hedral geometry. In the crystal, cations and anions are linked via weak N—H⋯Cl and C—H⋯Cl hydrogen bonds. Double layers of complex anions stack along the b- axis direction, which alternate with double layers of 4-(di­methyl­amino)-pyridinium cations.
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spelling pubmed-37724172013-09-17 4-(Di­methyl­amino)­pyridinium trichlorido[4-(di­methyl­amino)­pyridine-κN]cobaltate(II) Guenifa, Fatiha Hadjadj, Nasreddine Zeghouan, Ouahida Bendjeddou, Lamia Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the anion of the title compound, (C(7)H(11)N(2))[CoCl(3)(C(7)H(10)N(2))], the Co(II) ion is coordinated by one N atom from a 4-(di­methyl­amino)­pyridine (DMAP) ligand and three Cl atoms, forming a CoNCl(3) polyhedron with a distorted tetra­hedral geometry. In the crystal, cations and anions are linked via weak N—H⋯Cl and C—H⋯Cl hydrogen bonds. Double layers of complex anions stack along the b- axis direction, which alternate with double layers of 4-(di­methyl­amino)-pyridinium cations. International Union of Crystallography 2013-06-12 /pmc/articles/PMC3772417/ /pubmed/24046560 http://dx.doi.org/10.1107/S1600536813015602 Text en © Guenifa et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guenifa, Fatiha
Hadjadj, Nasreddine
Zeghouan, Ouahida
Bendjeddou, Lamia
Merazig, Hocine
4-(Di­methyl­amino)­pyridinium trichlorido[4-(di­methyl­amino)­pyridine-κN]cobaltate(II)
title 4-(Di­methyl­amino)­pyridinium trichlorido[4-(di­methyl­amino)­pyridine-κN]cobaltate(II)
title_full 4-(Di­methyl­amino)­pyridinium trichlorido[4-(di­methyl­amino)­pyridine-κN]cobaltate(II)
title_fullStr 4-(Di­methyl­amino)­pyridinium trichlorido[4-(di­methyl­amino)­pyridine-κN]cobaltate(II)
title_full_unstemmed 4-(Di­methyl­amino)­pyridinium trichlorido[4-(di­methyl­amino)­pyridine-κN]cobaltate(II)
title_short 4-(Di­methyl­amino)­pyridinium trichlorido[4-(di­methyl­amino)­pyridine-κN]cobaltate(II)
title_sort 4-(di­methyl­amino)­pyridinium trichlorido[4-(di­methyl­amino)­pyridine-κn]cobaltate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772417/
https://www.ncbi.nlm.nih.gov/pubmed/24046560
http://dx.doi.org/10.1107/S1600536813015602
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AT zeghouanouahida 4dimethylaminopyridiniumtrichlorido4dimethylaminopyridinekncobaltateii
AT bendjeddoulamia 4dimethylaminopyridiniumtrichlorido4dimethylaminopyridinekncobaltateii
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