catena-Poly[aqua­bis­(μ-3-chloro­benzo­ato-κ(2) O:O′)zinc]

In the polymeric title compound, [Zn(C(7)H(4)ClO(2))(2)(H(2)O)](n), the Zn(II) cation is located on a twofold rotation axis and is coordinated by carboxylate O atoms of four monodentate chloro­benzoate anions and by one water mol­ecule, located on a twofold rotation axis, in a distorted square-pyram...

Descripción completa

Detalles Bibliográficos
Autores principales: Bozkurt, Nihat, Dilek, Nefise, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772418/
https://www.ncbi.nlm.nih.gov/pubmed/24046561
http://dx.doi.org/10.1107/S160053681301564X
Descripción
Sumario:In the polymeric title compound, [Zn(C(7)H(4)ClO(2))(2)(H(2)O)](n), the Zn(II) cation is located on a twofold rotation axis and is coordinated by carboxylate O atoms of four monodentate chloro­benzoate anions and by one water mol­ecule, located on a twofold rotation axis, in a distorted square-pyramidal geometry. In the anion, the carboxyl­ate group is twisted away from the attached benzene ring by 44.16 (11)°. The chloro­benzoate anion bridges Zn(II) cations, forming polymeric chains running along the c-axis direction. O—H⋯O hydrogen bonds between coordinating water mol­ecules and carboxyl­ate groups link adjacent chains into layers parallel to the bc plane.

Ejemplares similares