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Poly[bis{μ-N′-[(pyridin-4-yl)methylidene]benzohydrazidato}copper(II)]
In the title complex, [Cu(C(13)H(10)N(3)O)(2)](n), the copper(II) cation is located on a crystallographic inversion centre and adopts an elongated octahedral coordination geometry with the equatorial plane provided by trans-arranged bis-N,O-chelating acylhydrazine groups from two ligands and the a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772419/ https://www.ncbi.nlm.nih.gov/pubmed/24046562 http://dx.doi.org/10.1107/S1600536813015882 |
Sumario: | In the title complex, [Cu(C(13)H(10)N(3)O)(2)](n), the copper(II) cation is located on a crystallographic inversion centre and adopts an elongated octahedral coordination geometry with the equatorial plane provided by trans-arranged bis-N,O-chelating acylhydrazine groups from two ligands and the apices by the N atoms of two pyridine rings belonging to symmetry-related ligands. The ligand adopts a Z conformation about the C=N double bond. The dihedral angle between the pyridine and phenyl rings is 2.99 (13)°. An intraligand C—H⋯N hydrogen bond is observed. In the crystal, each ligand bridges two adjacent metal ions, forming a (4,4) grid layered structure. π–π stacking interactions [centroid–centroid distances in the range 3.569 (4)–3.584 (9) Å] involving rings of adjacent layers result in the formation of a three-dimensional supramolecular network. |
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