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Poly[bis­{μ-N′-[(pyridin-4-yl)methyl­idene]benzohydrazidato}copper(II)]

In the title complex, [Cu(C(13)H(10)N(3)O)(2)](n), the copper(II) cation is located on a crystallographic inversion centre and adopts an elongated octa­hedral coordination geometry with the equatorial plane provided by trans-arranged bis-N,O-chelating acyl­hydrazine groups from two ligands and the a...

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Detalles Bibliográficos
Autores principales: Wu, Qiong, Chen, Da-Chi, Wu, Chu-Yi, Yan, Chang-Xiu, Liao, Jian-Zhen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772419/
https://www.ncbi.nlm.nih.gov/pubmed/24046562
http://dx.doi.org/10.1107/S1600536813015882
Descripción
Sumario:In the title complex, [Cu(C(13)H(10)N(3)O)(2)](n), the copper(II) cation is located on a crystallographic inversion centre and adopts an elongated octa­hedral coordination geometry with the equatorial plane provided by trans-arranged bis-N,O-chelating acyl­hydrazine groups from two ligands and the apices by the N atoms of two pyridine rings belonging to symmetry-related ligands. The ligand adopts a Z conformation about the C=N double bond. The dihedral angle between the pyridine and phenyl rings is 2.99 (13)°. An intra­ligand C—H⋯N hydrogen bond is observed. In the crystal, each ligand bridges two adjacent metal ions, forming a (4,4) grid layered structure. π–π stacking inter­actions [centroid–centroid distances in the range 3.569 (4)–3.584 (9) Å] involving rings of adjacent layers result in the formation of a three-dimensional supra­molecular network.