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Poly[bis­{μ-N′-[(pyridin-4-yl)methyl­idene]benzohydrazidato}copper(II)]

In the title complex, [Cu(C(13)H(10)N(3)O)(2)](n), the copper(II) cation is located on a crystallographic inversion centre and adopts an elongated octa­hedral coordination geometry with the equatorial plane provided by trans-arranged bis-N,O-chelating acyl­hydrazine groups from two ligands and the a...

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Autores principales: Wu, Qiong, Chen, Da-Chi, Wu, Chu-Yi, Yan, Chang-Xiu, Liao, Jian-Zhen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772419/
https://www.ncbi.nlm.nih.gov/pubmed/24046562
http://dx.doi.org/10.1107/S1600536813015882
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author Wu, Qiong
Chen, Da-Chi
Wu, Chu-Yi
Yan, Chang-Xiu
Liao, Jian-Zhen
author_facet Wu, Qiong
Chen, Da-Chi
Wu, Chu-Yi
Yan, Chang-Xiu
Liao, Jian-Zhen
author_sort Wu, Qiong
collection PubMed
description In the title complex, [Cu(C(13)H(10)N(3)O)(2)](n), the copper(II) cation is located on a crystallographic inversion centre and adopts an elongated octa­hedral coordination geometry with the equatorial plane provided by trans-arranged bis-N,O-chelating acyl­hydrazine groups from two ligands and the apices by the N atoms of two pyridine rings belonging to symmetry-related ligands. The ligand adopts a Z conformation about the C=N double bond. The dihedral angle between the pyridine and phenyl rings is 2.99 (13)°. An intra­ligand C—H⋯N hydrogen bond is observed. In the crystal, each ligand bridges two adjacent metal ions, forming a (4,4) grid layered structure. π–π stacking inter­actions [centroid–centroid distances in the range 3.569 (4)–3.584 (9) Å] involving rings of adjacent layers result in the formation of a three-dimensional supra­molecular network.
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spelling pubmed-37724192013-09-17 Poly[bis­{μ-N′-[(pyridin-4-yl)methyl­idene]benzohydrazidato}copper(II)] Wu, Qiong Chen, Da-Chi Wu, Chu-Yi Yan, Chang-Xiu Liao, Jian-Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(13)H(10)N(3)O)(2)](n), the copper(II) cation is located on a crystallographic inversion centre and adopts an elongated octa­hedral coordination geometry with the equatorial plane provided by trans-arranged bis-N,O-chelating acyl­hydrazine groups from two ligands and the apices by the N atoms of two pyridine rings belonging to symmetry-related ligands. The ligand adopts a Z conformation about the C=N double bond. The dihedral angle between the pyridine and phenyl rings is 2.99 (13)°. An intra­ligand C—H⋯N hydrogen bond is observed. In the crystal, each ligand bridges two adjacent metal ions, forming a (4,4) grid layered structure. π–π stacking inter­actions [centroid–centroid distances in the range 3.569 (4)–3.584 (9) Å] involving rings of adjacent layers result in the formation of a three-dimensional supra­molecular network. International Union of Crystallography 2013-06-15 /pmc/articles/PMC3772419/ /pubmed/24046562 http://dx.doi.org/10.1107/S1600536813015882 Text en © Wu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Qiong
Chen, Da-Chi
Wu, Chu-Yi
Yan, Chang-Xiu
Liao, Jian-Zhen
Poly[bis­{μ-N′-[(pyridin-4-yl)methyl­idene]benzohydrazidato}copper(II)]
title Poly[bis­{μ-N′-[(pyridin-4-yl)methyl­idene]benzohydrazidato}copper(II)]
title_full Poly[bis­{μ-N′-[(pyridin-4-yl)methyl­idene]benzohydrazidato}copper(II)]
title_fullStr Poly[bis­{μ-N′-[(pyridin-4-yl)methyl­idene]benzohydrazidato}copper(II)]
title_full_unstemmed Poly[bis­{μ-N′-[(pyridin-4-yl)methyl­idene]benzohydrazidato}copper(II)]
title_short Poly[bis­{μ-N′-[(pyridin-4-yl)methyl­idene]benzohydrazidato}copper(II)]
title_sort poly[bis­{μ-n′-[(pyridin-4-yl)methyl­idene]benzohydrazidato}copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772419/
https://www.ncbi.nlm.nih.gov/pubmed/24046562
http://dx.doi.org/10.1107/S1600536813015882
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