Cargando…
Poly[bis{μ-N′-[(pyridin-4-yl)methylidene]benzohydrazidato}copper(II)]
In the title complex, [Cu(C(13)H(10)N(3)O)(2)](n), the copper(II) cation is located on a crystallographic inversion centre and adopts an elongated octahedral coordination geometry with the equatorial plane provided by trans-arranged bis-N,O-chelating acylhydrazine groups from two ligands and the a...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772419/ https://www.ncbi.nlm.nih.gov/pubmed/24046562 http://dx.doi.org/10.1107/S1600536813015882 |
_version_ | 1782284324592156672 |
---|---|
author | Wu, Qiong Chen, Da-Chi Wu, Chu-Yi Yan, Chang-Xiu Liao, Jian-Zhen |
author_facet | Wu, Qiong Chen, Da-Chi Wu, Chu-Yi Yan, Chang-Xiu Liao, Jian-Zhen |
author_sort | Wu, Qiong |
collection | PubMed |
description | In the title complex, [Cu(C(13)H(10)N(3)O)(2)](n), the copper(II) cation is located on a crystallographic inversion centre and adopts an elongated octahedral coordination geometry with the equatorial plane provided by trans-arranged bis-N,O-chelating acylhydrazine groups from two ligands and the apices by the N atoms of two pyridine rings belonging to symmetry-related ligands. The ligand adopts a Z conformation about the C=N double bond. The dihedral angle between the pyridine and phenyl rings is 2.99 (13)°. An intraligand C—H⋯N hydrogen bond is observed. In the crystal, each ligand bridges two adjacent metal ions, forming a (4,4) grid layered structure. π–π stacking interactions [centroid–centroid distances in the range 3.569 (4)–3.584 (9) Å] involving rings of adjacent layers result in the formation of a three-dimensional supramolecular network. |
format | Online Article Text |
id | pubmed-3772419 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37724192013-09-17 Poly[bis{μ-N′-[(pyridin-4-yl)methylidene]benzohydrazidato}copper(II)] Wu, Qiong Chen, Da-Chi Wu, Chu-Yi Yan, Chang-Xiu Liao, Jian-Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(13)H(10)N(3)O)(2)](n), the copper(II) cation is located on a crystallographic inversion centre and adopts an elongated octahedral coordination geometry with the equatorial plane provided by trans-arranged bis-N,O-chelating acylhydrazine groups from two ligands and the apices by the N atoms of two pyridine rings belonging to symmetry-related ligands. The ligand adopts a Z conformation about the C=N double bond. The dihedral angle between the pyridine and phenyl rings is 2.99 (13)°. An intraligand C—H⋯N hydrogen bond is observed. In the crystal, each ligand bridges two adjacent metal ions, forming a (4,4) grid layered structure. π–π stacking interactions [centroid–centroid distances in the range 3.569 (4)–3.584 (9) Å] involving rings of adjacent layers result in the formation of a three-dimensional supramolecular network. International Union of Crystallography 2013-06-15 /pmc/articles/PMC3772419/ /pubmed/24046562 http://dx.doi.org/10.1107/S1600536813015882 Text en © Wu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wu, Qiong Chen, Da-Chi Wu, Chu-Yi Yan, Chang-Xiu Liao, Jian-Zhen Poly[bis{μ-N′-[(pyridin-4-yl)methylidene]benzohydrazidato}copper(II)] |
title | Poly[bis{μ-N′-[(pyridin-4-yl)methylidene]benzohydrazidato}copper(II)] |
title_full | Poly[bis{μ-N′-[(pyridin-4-yl)methylidene]benzohydrazidato}copper(II)] |
title_fullStr | Poly[bis{μ-N′-[(pyridin-4-yl)methylidene]benzohydrazidato}copper(II)] |
title_full_unstemmed | Poly[bis{μ-N′-[(pyridin-4-yl)methylidene]benzohydrazidato}copper(II)] |
title_short | Poly[bis{μ-N′-[(pyridin-4-yl)methylidene]benzohydrazidato}copper(II)] |
title_sort | poly[bis{μ-n′-[(pyridin-4-yl)methylidene]benzohydrazidato}copper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772419/ https://www.ncbi.nlm.nih.gov/pubmed/24046562 http://dx.doi.org/10.1107/S1600536813015882 |
work_keys_str_mv | AT wuqiong polybismnpyridin4ylmethylidenebenzohydrazidatocopperii AT chendachi polybismnpyridin4ylmethylidenebenzohydrazidatocopperii AT wuchuyi polybismnpyridin4ylmethylidenebenzohydrazidatocopperii AT yanchangxiu polybismnpyridin4ylmethylidenebenzohydrazidatocopperii AT liaojianzhen polybismnpyridin4ylmethylidenebenzohydrazidatocopperii |