Bis(dicyanamido-κN)[tris­(3-amino­propyl)amine-κ(4) N]nickel(II)

In the title complex, [Ni(C(2)N(3))(2)(C(9)H(24)N(4))], the Ni(II) atom is coordinated in a distorted octa­hedral geometry by one tris­(3-amino­prop­yl)amine (tris­apa) ligand and two dicyanamide (dca) ligands [one of them disordered in a 0.681 (19):0319 (19) ratio]. Inter­molecular N—H⋯N hydrogen b...

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Detalles Bibliográficos
Autores principales: Luo, Jun, Zhang, Xin-Rong, Qiu, Li-Juan, Yang, Feng, Liu, Bao-Shu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772421/
https://www.ncbi.nlm.nih.gov/pubmed/24046564
http://dx.doi.org/10.1107/S1600536813015651
Descripción
Sumario:In the title complex, [Ni(C(2)N(3))(2)(C(9)H(24)N(4))], the Ni(II) atom is coordinated in a distorted octa­hedral geometry by one tris­(3-amino­prop­yl)amine (tris­apa) ligand and two dicyanamide (dca) ligands [one of them disordered in a 0.681 (19):0319 (19) ratio]. Inter­molecular N—H⋯N hydrogen bonds involving the N atoms of the dca anions and the tris­apa amine H atoms result in the formation of a three-dimensional network.

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