Bis(dicyanamido-κN)[tris­(3-amino­propyl)amine-κ(4) N]nickel(II)

In the title complex, [Ni(C(2)N(3))(2)(C(9)H(24)N(4))], the Ni(II) atom is coordinated in a distorted octa­hedral geometry by one tris­(3-amino­prop­yl)amine (tris­apa) ligand and two dicyanamide (dca) ligands [one of them disordered in a 0.681 (19):0319 (19) ratio]. Inter­molecular N—H⋯N hydrogen b...

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Detalles Bibliográficos
Autores principales: Luo, Jun, Zhang, Xin-Rong, Qiu, Li-Juan, Yang, Feng, Liu, Bao-Shu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772421/
https://www.ncbi.nlm.nih.gov/pubmed/24046564
http://dx.doi.org/10.1107/S1600536813015651
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author Luo, Jun
Zhang, Xin-Rong
Qiu, Li-Juan
Yang, Feng
Liu, Bao-Shu
author_facet Luo, Jun
Zhang, Xin-Rong
Qiu, Li-Juan
Yang, Feng
Liu, Bao-Shu
author_sort Luo, Jun
collection PubMed
description In the title complex, [Ni(C(2)N(3))(2)(C(9)H(24)N(4))], the Ni(II) atom is coordinated in a distorted octa­hedral geometry by one tris­(3-amino­prop­yl)amine (tris­apa) ligand and two dicyanamide (dca) ligands [one of them disordered in a 0.681 (19):0319 (19) ratio]. Inter­molecular N—H⋯N hydrogen bonds involving the N atoms of the dca anions and the tris­apa amine H atoms result in the formation of a three-dimensional network.
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spelling pubmed-37724212013-09-17 Bis(dicyanamido-κN)[tris­(3-amino­propyl)amine-κ(4) N]nickel(II) Luo, Jun Zhang, Xin-Rong Qiu, Li-Juan Yang, Feng Liu, Bao-Shu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(2)N(3))(2)(C(9)H(24)N(4))], the Ni(II) atom is coordinated in a distorted octa­hedral geometry by one tris­(3-amino­prop­yl)amine (tris­apa) ligand and two dicyanamide (dca) ligands [one of them disordered in a 0.681 (19):0319 (19) ratio]. Inter­molecular N—H⋯N hydrogen bonds involving the N atoms of the dca anions and the tris­apa amine H atoms result in the formation of a three-dimensional network. International Union of Crystallography 2013-06-15 /pmc/articles/PMC3772421/ /pubmed/24046564 http://dx.doi.org/10.1107/S1600536813015651 Text en © Luo et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Luo, Jun
Zhang, Xin-Rong
Qiu, Li-Juan
Yang, Feng
Liu, Bao-Shu
Bis(dicyanamido-κN)[tris­(3-amino­propyl)amine-κ(4) N]nickel(II)
title Bis(dicyanamido-κN)[tris­(3-amino­propyl)amine-κ(4) N]nickel(II)
title_full Bis(dicyanamido-κN)[tris­(3-amino­propyl)amine-κ(4) N]nickel(II)
title_fullStr Bis(dicyanamido-κN)[tris­(3-amino­propyl)amine-κ(4) N]nickel(II)
title_full_unstemmed Bis(dicyanamido-κN)[tris­(3-amino­propyl)amine-κ(4) N]nickel(II)
title_short Bis(dicyanamido-κN)[tris­(3-amino­propyl)amine-κ(4) N]nickel(II)
title_sort bis(dicyanamido-κn)[tris­(3-amino­propyl)amine-κ(4) n]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772421/
https://www.ncbi.nlm.nih.gov/pubmed/24046564
http://dx.doi.org/10.1107/S1600536813015651
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