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Di-μ-nicotinamide-κ(2) N (1):O;κ(2) O:N (1)-bis[aquabis(3-chlorobenzoato-κ(2) O,O′)cadmium]
In the centrosymmetric dinuclear title compound, [Cd(2)(C(7)H(4)ClO(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cd(II) atom is coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, four O atoms from two 3-chlorobenzo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772423/ https://www.ncbi.nlm.nih.gov/pubmed/24046566 http://dx.doi.org/10.1107/S1600536813015948 |
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author | Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Bozkurt, Nihat |
collection | PubMed |
description | In the centrosymmetric dinuclear title compound, [Cd(2)(C(7)H(4)ClO(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cd(II) atom is coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, four O atoms from two 3-chlorobenzoate ligands and one water molecule in an irregular geometry. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 6.98 (12) and 2.42 (13)°, while the benzene rings are oriented at a dihedral angle of 4.33 (6)°. Intermolecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. π–π interactions, indicated by short centroid–centroid distances [3.892 (1) Å between the pyridine rings and 3.683 (1) Å between the benzene rings] further stabilize the structure. |
format | Online Article Text |
id | pubmed-3772423 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37724232013-09-17 Di-μ-nicotinamide-κ(2) N (1):O;κ(2) O:N (1)-bis[aquabis(3-chlorobenzoato-κ(2) O,O′)cadmium] Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title compound, [Cd(2)(C(7)H(4)ClO(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cd(II) atom is coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, four O atoms from two 3-chlorobenzoate ligands and one water molecule in an irregular geometry. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 6.98 (12) and 2.42 (13)°, while the benzene rings are oriented at a dihedral angle of 4.33 (6)°. Intermolecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. π–π interactions, indicated by short centroid–centroid distances [3.892 (1) Å between the pyridine rings and 3.683 (1) Å between the benzene rings] further stabilize the structure. International Union of Crystallography 2013-06-15 /pmc/articles/PMC3772423/ /pubmed/24046566 http://dx.doi.org/10.1107/S1600536813015948 Text en © Bozkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Di-μ-nicotinamide-κ(2) N (1):O;κ(2) O:N (1)-bis[aquabis(3-chlorobenzoato-κ(2) O,O′)cadmium] |
title | Di-μ-nicotinamide-κ(2)
N
(1):O;κ(2)
O:N
(1)-bis[aquabis(3-chlorobenzoato-κ(2)
O,O′)cadmium] |
title_full | Di-μ-nicotinamide-κ(2)
N
(1):O;κ(2)
O:N
(1)-bis[aquabis(3-chlorobenzoato-κ(2)
O,O′)cadmium] |
title_fullStr | Di-μ-nicotinamide-κ(2)
N
(1):O;κ(2)
O:N
(1)-bis[aquabis(3-chlorobenzoato-κ(2)
O,O′)cadmium] |
title_full_unstemmed | Di-μ-nicotinamide-κ(2)
N
(1):O;κ(2)
O:N
(1)-bis[aquabis(3-chlorobenzoato-κ(2)
O,O′)cadmium] |
title_short | Di-μ-nicotinamide-κ(2)
N
(1):O;κ(2)
O:N
(1)-bis[aquabis(3-chlorobenzoato-κ(2)
O,O′)cadmium] |
title_sort | di-μ-nicotinamide-κ(2)
n
(1):o;κ(2)
o:n
(1)-bis[aquabis(3-chlorobenzoato-κ(2)
o,o′)cadmium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772423/ https://www.ncbi.nlm.nih.gov/pubmed/24046566 http://dx.doi.org/10.1107/S1600536813015948 |
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