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Di-μ-nicotinamide-κ(2) N (1):O;κ(2) O:N (1)-bis­[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]

In the centrosymmetric dinuclear title compound, [Cd(2)(C(7)H(4)ClO(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cd(II) atom is coord­inated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, four O atoms from two 3-chloro­benzo...

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Autores principales: Bozkurt, Nihat, Dilek, Nefise, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772423/
https://www.ncbi.nlm.nih.gov/pubmed/24046566
http://dx.doi.org/10.1107/S1600536813015948
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author Bozkurt, Nihat
Dilek, Nefise
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Bozkurt, Nihat
Dilek, Nefise
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Bozkurt, Nihat
collection PubMed
description In the centrosymmetric dinuclear title compound, [Cd(2)(C(7)H(4)ClO(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cd(II) atom is coord­inated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, four O atoms from two 3-chloro­benzoate ligands and one water mol­ecule in an irregular geometry. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 6.98 (12) and 2.42 (13)°, while the benzene rings are oriented at a dihedral angle of 4.33 (6)°. Inter­molecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. π–π inter­actions, indicated by short centroid–centroid distances [3.892 (1) Å between the pyridine rings and 3.683 (1) Å between the benzene rings] further stabilize the structure.
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spelling pubmed-37724232013-09-17 Di-μ-nicotinamide-κ(2) N (1):O;κ(2) O:N (1)-bis­[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium] Bozkurt, Nihat Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title compound, [Cd(2)(C(7)H(4)ClO(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Cd(II) atom is coord­inated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, four O atoms from two 3-chloro­benzoate ligands and one water mol­ecule in an irregular geometry. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 6.98 (12) and 2.42 (13)°, while the benzene rings are oriented at a dihedral angle of 4.33 (6)°. Inter­molecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. π–π inter­actions, indicated by short centroid–centroid distances [3.892 (1) Å between the pyridine rings and 3.683 (1) Å between the benzene rings] further stabilize the structure. International Union of Crystallography 2013-06-15 /pmc/articles/PMC3772423/ /pubmed/24046566 http://dx.doi.org/10.1107/S1600536813015948 Text en © Bozkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bozkurt, Nihat
Dilek, Nefise
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
Di-μ-nicotinamide-κ(2) N (1):O;κ(2) O:N (1)-bis­[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]
title Di-μ-nicotinamide-κ(2) N (1):O;κ(2) O:N (1)-bis­[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]
title_full Di-μ-nicotinamide-κ(2) N (1):O;κ(2) O:N (1)-bis­[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]
title_fullStr Di-μ-nicotinamide-κ(2) N (1):O;κ(2) O:N (1)-bis­[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]
title_full_unstemmed Di-μ-nicotinamide-κ(2) N (1):O;κ(2) O:N (1)-bis­[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]
title_short Di-μ-nicotinamide-κ(2) N (1):O;κ(2) O:N (1)-bis­[aqua­bis­(3-chloro­benzoato-κ(2) O,O′)cadmium]
title_sort di-μ-nicotinamide-κ(2) n (1):o;κ(2) o:n (1)-bis­[aqua­bis­(3-chloro­benzoato-κ(2) o,o′)cadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772423/
https://www.ncbi.nlm.nih.gov/pubmed/24046566
http://dx.doi.org/10.1107/S1600536813015948
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