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cis-Dichloridotetrakis(dimethyl sulfoxide-κO)chromium(III) chloride dimethyl sulfoxide monosolvate
The structure of the title compound, [CrCl(2)(C(2)H(6)OS)(4)]Cl·C(2)H(6)OS, consists of a Cr(III) ion coordinated by four O atoms of dimethyl sulfoxide (DMSO) ligands and two chloride ions in cis positions, forming a distorted CrCl(2)O(4) octahedron. An isolated Cl(−) counter-anion and a positional...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772426/ https://www.ncbi.nlm.nih.gov/pubmed/24046569 http://dx.doi.org/10.1107/S160053681301622X |
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| author | Al-Najjar, Nada A. Al-Sudani, Abdul-Razak H. Shanshal, Muthana A. Mousa, Falih H. Kariuki, Benson M. |
| author_facet | Al-Najjar, Nada A. Al-Sudani, Abdul-Razak H. Shanshal, Muthana A. Mousa, Falih H. Kariuki, Benson M. |
| author_sort | Al-Najjar, Nada A. |
| collection | PubMed |
| description | The structure of the title compound, [CrCl(2)(C(2)H(6)OS)(4)]Cl·C(2)H(6)OS, consists of a Cr(III) ion coordinated by four O atoms of dimethyl sulfoxide (DMSO) ligands and two chloride ions in cis positions, forming a distorted CrCl(2)O(4) octahedron. An isolated Cl(−) counter-anion and a positionally disordered DMSO molecule [occupancy ratio 0.654 (4):0.346 (4)] are also present. In the structure, the complex cations interact with the Cl(−) counter-anions and the DMSO solvent molecules via weak C—H⋯Cl and C—H⋯O interactions, forming a three-dimensional network. |
| format | Online Article Text |
| id | pubmed-3772426 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-37724262013-09-17 cis-Dichloridotetrakis(dimethyl sulfoxide-κO)chromium(III) chloride dimethyl sulfoxide monosolvate Al-Najjar, Nada A. Al-Sudani, Abdul-Razak H. Shanshal, Muthana A. Mousa, Falih H. Kariuki, Benson M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [CrCl(2)(C(2)H(6)OS)(4)]Cl·C(2)H(6)OS, consists of a Cr(III) ion coordinated by four O atoms of dimethyl sulfoxide (DMSO) ligands and two chloride ions in cis positions, forming a distorted CrCl(2)O(4) octahedron. An isolated Cl(−) counter-anion and a positionally disordered DMSO molecule [occupancy ratio 0.654 (4):0.346 (4)] are also present. In the structure, the complex cations interact with the Cl(−) counter-anions and the DMSO solvent molecules via weak C—H⋯Cl and C—H⋯O interactions, forming a three-dimensional network. International Union of Crystallography 2013-06-15 /pmc/articles/PMC3772426/ /pubmed/24046569 http://dx.doi.org/10.1107/S160053681301622X Text en © Al-Najjar et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Al-Najjar, Nada A. Al-Sudani, Abdul-Razak H. Shanshal, Muthana A. Mousa, Falih H. Kariuki, Benson M. cis-Dichloridotetrakis(dimethyl sulfoxide-κO)chromium(III) chloride dimethyl sulfoxide monosolvate |
| title |
cis-Dichloridotetrakis(dimethyl sulfoxide-κO)chromium(III) chloride dimethyl sulfoxide monosolvate |
| title_full |
cis-Dichloridotetrakis(dimethyl sulfoxide-κO)chromium(III) chloride dimethyl sulfoxide monosolvate |
| title_fullStr |
cis-Dichloridotetrakis(dimethyl sulfoxide-κO)chromium(III) chloride dimethyl sulfoxide monosolvate |
| title_full_unstemmed |
cis-Dichloridotetrakis(dimethyl sulfoxide-κO)chromium(III) chloride dimethyl sulfoxide monosolvate |
| title_short |
cis-Dichloridotetrakis(dimethyl sulfoxide-κO)chromium(III) chloride dimethyl sulfoxide monosolvate |
| title_sort | cis-dichloridotetrakis(dimethyl sulfoxide-κo)chromium(iii) chloride dimethyl sulfoxide monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772426/ https://www.ncbi.nlm.nih.gov/pubmed/24046569 http://dx.doi.org/10.1107/S160053681301622X |
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