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catena-Poly[bis(μ(3)-2-phenylacetato-κ(3) O,O′:O)bis(μ(2)-2-phenylacetato-κ(2) O:O′)dicopper(II)(Cu—Cu)]
The title polymeric compound, [Cu(2)(C(8)H(7)O(2))(4)](n), was synthesized by the reaction of copper acetate with aqueous phenylacetic acid. The unique Cu(II) atom is coordinated by five O atoms from the carboxylate groups of phenylacetate ligands, and the strongly distorted octahedral coordinat...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772427/ https://www.ncbi.nlm.nih.gov/pubmed/24046570 http://dx.doi.org/10.1107/S160053681301581X |
Sumario: | The title polymeric compound, [Cu(2)(C(8)H(7)O(2))(4)](n), was synthesized by the reaction of copper acetate with aqueous phenylacetic acid. The unique Cu(II) atom is coordinated by five O atoms from the carboxylate groups of phenylacetate ligands, and the strongly distorted octahedral coordination environment is completed by a Cu—Cu bond of 2.581 (2) Å, at whose mid-point is located an inversion centre. The crystal structure consists of infinite polymeric linear chains of Cu(2+) ions, running along [100], linked by bridging phenylacetate groups. |
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