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catena-Poly[bis­(μ(3)-2-phenyl­acetato-κ(3) O,O′:O)bis­(μ(2)-2-phenyl­acetato-κ(2) O:O′)dicopper(II)(Cu—Cu)]

The title polymeric compound, [Cu(2)(C(8)H(7)O(2))(4)](n), was synthesized by the reaction of copper acetate with aqueous phenyl­acetic acid. The unique Cu(II) atom is coordinated by five O atoms from the carboxyl­ate groups of phenyl­acetate ligands, and the strongly distorted octa­hedral coordinat...

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Detalles Bibliográficos
Autores principales: Benslimane, Meriem, Redjel, Yasmine Kheira, Merazig, Hocine, Daran, Jean-Claude
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772427/
https://www.ncbi.nlm.nih.gov/pubmed/24046570
http://dx.doi.org/10.1107/S160053681301581X
Descripción
Sumario:The title polymeric compound, [Cu(2)(C(8)H(7)O(2))(4)](n), was synthesized by the reaction of copper acetate with aqueous phenyl­acetic acid. The unique Cu(II) atom is coordinated by five O atoms from the carboxyl­ate groups of phenyl­acetate ligands, and the strongly distorted octa­hedral coordination environment is completed by a Cu—Cu bond of 2.581 (2) Å, at whose mid-point is located an inversion centre. The crystal structure consists of infinite polymeric linear chains of Cu(2+) ions, running along [100], linked by bridging phenyl­acetate groups.