Cargando…
catena-Poly[bis(μ(3)-2-phenylacetato-κ(3) O,O′:O)bis(μ(2)-2-phenylacetato-κ(2) O:O′)dicopper(II)(Cu—Cu)]
The title polymeric compound, [Cu(2)(C(8)H(7)O(2))(4)](n), was synthesized by the reaction of copper acetate with aqueous phenylacetic acid. The unique Cu(II) atom is coordinated by five O atoms from the carboxylate groups of phenylacetate ligands, and the strongly distorted octahedral coordinat...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772427/ https://www.ncbi.nlm.nih.gov/pubmed/24046570 http://dx.doi.org/10.1107/S160053681301581X |
| _version_ | 1782284326498467840 |
|---|---|
| author | Benslimane, Meriem Redjel, Yasmine Kheira Merazig, Hocine Daran, Jean-Claude |
| author_facet | Benslimane, Meriem Redjel, Yasmine Kheira Merazig, Hocine Daran, Jean-Claude |
| author_sort | Benslimane, Meriem |
| collection | PubMed |
| description | The title polymeric compound, [Cu(2)(C(8)H(7)O(2))(4)](n), was synthesized by the reaction of copper acetate with aqueous phenylacetic acid. The unique Cu(II) atom is coordinated by five O atoms from the carboxylate groups of phenylacetate ligands, and the strongly distorted octahedral coordination environment is completed by a Cu—Cu bond of 2.581 (2) Å, at whose mid-point is located an inversion centre. The crystal structure consists of infinite polymeric linear chains of Cu(2+) ions, running along [100], linked by bridging phenylacetate groups. |
| format | Online Article Text |
| id | pubmed-3772427 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-37724272013-09-17 catena-Poly[bis(μ(3)-2-phenylacetato-κ(3) O,O′:O)bis(μ(2)-2-phenylacetato-κ(2) O:O′)dicopper(II)(Cu—Cu)] Benslimane, Meriem Redjel, Yasmine Kheira Merazig, Hocine Daran, Jean-Claude Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title polymeric compound, [Cu(2)(C(8)H(7)O(2))(4)](n), was synthesized by the reaction of copper acetate with aqueous phenylacetic acid. The unique Cu(II) atom is coordinated by five O atoms from the carboxylate groups of phenylacetate ligands, and the strongly distorted octahedral coordination environment is completed by a Cu—Cu bond of 2.581 (2) Å, at whose mid-point is located an inversion centre. The crystal structure consists of infinite polymeric linear chains of Cu(2+) ions, running along [100], linked by bridging phenylacetate groups. International Union of Crystallography 2013-06-15 /pmc/articles/PMC3772427/ /pubmed/24046570 http://dx.doi.org/10.1107/S160053681301581X Text en © Benslimane et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Benslimane, Meriem Redjel, Yasmine Kheira Merazig, Hocine Daran, Jean-Claude catena-Poly[bis(μ(3)-2-phenylacetato-κ(3) O,O′:O)bis(μ(2)-2-phenylacetato-κ(2) O:O′)dicopper(II)(Cu—Cu)] |
| title |
catena-Poly[bis(μ(3)-2-phenylacetato-κ(3)
O,O′:O)bis(μ(2)-2-phenylacetato-κ(2)
O:O′)dicopper(II)(Cu—Cu)] |
| title_full |
catena-Poly[bis(μ(3)-2-phenylacetato-κ(3)
O,O′:O)bis(μ(2)-2-phenylacetato-κ(2)
O:O′)dicopper(II)(Cu—Cu)] |
| title_fullStr |
catena-Poly[bis(μ(3)-2-phenylacetato-κ(3)
O,O′:O)bis(μ(2)-2-phenylacetato-κ(2)
O:O′)dicopper(II)(Cu—Cu)] |
| title_full_unstemmed |
catena-Poly[bis(μ(3)-2-phenylacetato-κ(3)
O,O′:O)bis(μ(2)-2-phenylacetato-κ(2)
O:O′)dicopper(II)(Cu—Cu)] |
| title_short |
catena-Poly[bis(μ(3)-2-phenylacetato-κ(3)
O,O′:O)bis(μ(2)-2-phenylacetato-κ(2)
O:O′)dicopper(II)(Cu—Cu)] |
| title_sort | catena-poly[bis(μ(3)-2-phenylacetato-κ(3)
o,o′:o)bis(μ(2)-2-phenylacetato-κ(2)
o:o′)dicopper(ii)(cu—cu)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772427/ https://www.ncbi.nlm.nih.gov/pubmed/24046570 http://dx.doi.org/10.1107/S160053681301581X |
| work_keys_str_mv | AT benslimanemeriem catenapolybism32phenylacetatok3ooobism22phenylacetatok2oodicopperiicucu AT redjelyasminekheira catenapolybism32phenylacetatok3ooobism22phenylacetatok2oodicopperiicucu AT merazighocine catenapolybism32phenylacetatok3ooobism22phenylacetatok2oodicopperiicucu AT daranjeanclaude catenapolybism32phenylacetatok3ooobism22phenylacetatok2oodicopperiicucu |