Poly[(aceto­nitrile-κN)-μ(3)-thio­cyanato-κ(3) N:S:S-μ(2)-thio­cyanato-κ(2) N:S-cadmium]

The asymmetric unit of the title compound, [Cd(NCS)(2)(CH(3)CN)](n), consists of one Cd(II) cation, two thio­cyanate anions and one aceto­nitrile ligand, all in general positions. The Cd(II) cation is coordinated by three N atoms of two thio­cyanate anions and one aceto­nitrile ligand, as well as th...

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Detalles Bibliográficos
Autores principales: Reinert, Thorben, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772428/
https://www.ncbi.nlm.nih.gov/pubmed/24046571
http://dx.doi.org/10.1107/S1600536813015870
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author Reinert, Thorben
Jess, Inke
Näther, Christian
author_facet Reinert, Thorben
Jess, Inke
Näther, Christian
author_sort Reinert, Thorben
collection PubMed
description The asymmetric unit of the title compound, [Cd(NCS)(2)(CH(3)CN)](n), consists of one Cd(II) cation, two thio­cyanate anions and one aceto­nitrile ligand, all in general positions. The Cd(II) cation is coordinated by three N atoms of two thio­cyanate anions and one aceto­nitrile ligand, as well as three S atoms of symmetry-related thio­cyanate anions within a slightly distorted octa­hedral coordination environment. The Cd(II) cations are linked by μ-1,3(N,S) and μ-1,1,3(S,S,N) thio­cyanate anions into layers that are located in the ab plane.
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spelling pubmed-37724282013-09-17 Poly[(aceto­nitrile-κN)-μ(3)-thio­cyanato-κ(3) N:S:S-μ(2)-thio­cyanato-κ(2) N:S-cadmium] Reinert, Thorben Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cd(NCS)(2)(CH(3)CN)](n), consists of one Cd(II) cation, two thio­cyanate anions and one aceto­nitrile ligand, all in general positions. The Cd(II) cation is coordinated by three N atoms of two thio­cyanate anions and one aceto­nitrile ligand, as well as three S atoms of symmetry-related thio­cyanate anions within a slightly distorted octa­hedral coordination environment. The Cd(II) cations are linked by μ-1,3(N,S) and μ-1,1,3(S,S,N) thio­cyanate anions into layers that are located in the ab plane. International Union of Crystallography 2013-06-15 /pmc/articles/PMC3772428/ /pubmed/24046571 http://dx.doi.org/10.1107/S1600536813015870 Text en © Reinert et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Reinert, Thorben
Jess, Inke
Näther, Christian
Poly[(aceto­nitrile-κN)-μ(3)-thio­cyanato-κ(3) N:S:S-μ(2)-thio­cyanato-κ(2) N:S-cadmium]
title Poly[(aceto­nitrile-κN)-μ(3)-thio­cyanato-κ(3) N:S:S-μ(2)-thio­cyanato-κ(2) N:S-cadmium]
title_full Poly[(aceto­nitrile-κN)-μ(3)-thio­cyanato-κ(3) N:S:S-μ(2)-thio­cyanato-κ(2) N:S-cadmium]
title_fullStr Poly[(aceto­nitrile-κN)-μ(3)-thio­cyanato-κ(3) N:S:S-μ(2)-thio­cyanato-κ(2) N:S-cadmium]
title_full_unstemmed Poly[(aceto­nitrile-κN)-μ(3)-thio­cyanato-κ(3) N:S:S-μ(2)-thio­cyanato-κ(2) N:S-cadmium]
title_short Poly[(aceto­nitrile-κN)-μ(3)-thio­cyanato-κ(3) N:S:S-μ(2)-thio­cyanato-κ(2) N:S-cadmium]
title_sort poly[(aceto­nitrile-κn)-μ(3)-thio­cyanato-κ(3) n:s:s-μ(2)-thio­cyanato-κ(2) n:s-cadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772428/
https://www.ncbi.nlm.nih.gov/pubmed/24046571
http://dx.doi.org/10.1107/S1600536813015870
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AT natherchristian polyacetonitrileknm3thiocyanatok3nssm2thiocyanatok2nscadmium

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