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Di­aqua­{2,2′-dimeth­oxy-6,6′-[(1E,1′E)-propane-1,3-diylbis(aza­nylyl­idene)bis­(methanylyl­idene)]diphenolato}nickel(II)

In the mol­ecule of the title compound, [Ni(C(19)H(20)N(2)O(4))(H(2)O)(2)], the central Ni(II) ion lies on a mirror plane and is surrounded by an N(2)O(4) coordination set in the form of a distorted octa­hedron defined by the O atoms of two water mol­ecules and by two phenolic O and two imine N atom...

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Detalles Bibliográficos
Autores principales: Datta, Amitabha, Machura, Barbara, Huang, Jui-Hsien, Sheu, Shiann-Cherng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772429/
https://www.ncbi.nlm.nih.gov/pubmed/24046572
http://dx.doi.org/10.1107/S1600536813016188
Descripción
Sumario:In the mol­ecule of the title compound, [Ni(C(19)H(20)N(2)O(4))(H(2)O)(2)], the central Ni(II) ion lies on a mirror plane and is surrounded by an N(2)O(4) coordination set in the form of a distorted octa­hedron defined by the O atoms of two water mol­ecules and by two phenolic O and two imine N atoms of the tetra­dentate Schiff base ligand. In the crystal, O—H⋯O hydrogen bonds between the water mol­ecules and the phenolic and meth­oxy O atoms of neighbouring mol­ecules lead to the formation of rods propagating parallel to [100].