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Diaqua{2,2′-dimethoxy-6,6′-[(1E,1′E)-propane-1,3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II)
In the molecule of the title compound, [Ni(C(19)H(20)N(2)O(4))(H(2)O)(2)], the central Ni(II) ion lies on a mirror plane and is surrounded by an N(2)O(4) coordination set in the form of a distorted octahedron defined by the O atoms of two water molecules and by two phenolic O and two imine N atom...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772429/ https://www.ncbi.nlm.nih.gov/pubmed/24046572 http://dx.doi.org/10.1107/S1600536813016188 |
Sumario: | In the molecule of the title compound, [Ni(C(19)H(20)N(2)O(4))(H(2)O)(2)], the central Ni(II) ion lies on a mirror plane and is surrounded by an N(2)O(4) coordination set in the form of a distorted octahedron defined by the O atoms of two water molecules and by two phenolic O and two imine N atoms of the tetradentate Schiff base ligand. In the crystal, O—H⋯O hydrogen bonds between the water molecules and the phenolic and methoxy O atoms of neighbouring molecules lead to the formation of rods propagating parallel to [100]. |
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