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Diaqua{2,2′-dimethoxy-6,6′-[(1E,1′E)-propane-1,3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II)
In the molecule of the title compound, [Ni(C(19)H(20)N(2)O(4))(H(2)O)(2)], the central Ni(II) ion lies on a mirror plane and is surrounded by an N(2)O(4) coordination set in the form of a distorted octahedron defined by the O atoms of two water molecules and by two phenolic O and two imine N atom...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772429/ https://www.ncbi.nlm.nih.gov/pubmed/24046572 http://dx.doi.org/10.1107/S1600536813016188 |
| _version_ | 1782284326939918336 |
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| author | Datta, Amitabha Machura, Barbara Huang, Jui-Hsien Sheu, Shiann-Cherng |
| author_facet | Datta, Amitabha Machura, Barbara Huang, Jui-Hsien Sheu, Shiann-Cherng |
| author_sort | Datta, Amitabha |
| collection | PubMed |
| description | In the molecule of the title compound, [Ni(C(19)H(20)N(2)O(4))(H(2)O)(2)], the central Ni(II) ion lies on a mirror plane and is surrounded by an N(2)O(4) coordination set in the form of a distorted octahedron defined by the O atoms of two water molecules and by two phenolic O and two imine N atoms of the tetradentate Schiff base ligand. In the crystal, O—H⋯O hydrogen bonds between the water molecules and the phenolic and methoxy O atoms of neighbouring molecules lead to the formation of rods propagating parallel to [100]. |
| format | Online Article Text |
| id | pubmed-3772429 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-37724292013-09-17 Diaqua{2,2′-dimethoxy-6,6′-[(1E,1′E)-propane-1,3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II) Datta, Amitabha Machura, Barbara Huang, Jui-Hsien Sheu, Shiann-Cherng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the molecule of the title compound, [Ni(C(19)H(20)N(2)O(4))(H(2)O)(2)], the central Ni(II) ion lies on a mirror plane and is surrounded by an N(2)O(4) coordination set in the form of a distorted octahedron defined by the O atoms of two water molecules and by two phenolic O and two imine N atoms of the tetradentate Schiff base ligand. In the crystal, O—H⋯O hydrogen bonds between the water molecules and the phenolic and methoxy O atoms of neighbouring molecules lead to the formation of rods propagating parallel to [100]. International Union of Crystallography 2013-06-15 /pmc/articles/PMC3772429/ /pubmed/24046572 http://dx.doi.org/10.1107/S1600536813016188 Text en © Datta et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Datta, Amitabha Machura, Barbara Huang, Jui-Hsien Sheu, Shiann-Cherng Diaqua{2,2′-dimethoxy-6,6′-[(1E,1′E)-propane-1,3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II) |
| title | Diaqua{2,2′-dimethoxy-6,6′-[(1E,1′E)-propane-1,3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II) |
| title_full | Diaqua{2,2′-dimethoxy-6,6′-[(1E,1′E)-propane-1,3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II) |
| title_fullStr | Diaqua{2,2′-dimethoxy-6,6′-[(1E,1′E)-propane-1,3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II) |
| title_full_unstemmed | Diaqua{2,2′-dimethoxy-6,6′-[(1E,1′E)-propane-1,3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II) |
| title_short | Diaqua{2,2′-dimethoxy-6,6′-[(1E,1′E)-propane-1,3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(II) |
| title_sort | diaqua{2,2′-dimethoxy-6,6′-[(1e,1′e)-propane-1,3-diylbis(azanylylidene)bis(methanylylidene)]diphenolato}nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772429/ https://www.ncbi.nlm.nih.gov/pubmed/24046572 http://dx.doi.org/10.1107/S1600536813016188 |
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