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Poly[dimethylammonium [(μ(2)-benzene-1,2-dicarboxylato-κ(2) O (1):O (3))[μ(2)-3-(pyridin-4-yl)-1H-pyrazol-1-ido-κ(2) N (1):N (3)]cuprate(II)]]
In the title complex, {(C(2)H(8)N)[Cu(C(8)H(4)O(4))(C(8)H(6)N(3))]}(n), there are two Cu(II) cations (each located on a centre of inversion), one benzene-1,2-dicarboxylate dianion, one 3-(pyridin-4-yl)-1H-pyrazol-1-ide anion and one dimethylammonium cation in the asymmetric unit. The dimethyla...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772430/ https://www.ncbi.nlm.nih.gov/pubmed/24046573 http://dx.doi.org/10.1107/S1600536813016334 |
Sumario: | In the title complex, {(C(2)H(8)N)[Cu(C(8)H(4)O(4))(C(8)H(6)N(3))]}(n), there are two Cu(II) cations (each located on a centre of inversion), one benzene-1,2-dicarboxylate dianion, one 3-(pyridin-4-yl)-1H-pyrazol-1-ide anion and one dimethylammonium cation in the asymmetric unit. The dimethylammonium cation was highly disordered and was treated with the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the crystallographic data takes into account the presence of the cation. Each Cu(II) cation exhibits a square-planar coordination geometry. A benzene-1,2-dicarboxylate dianion bridges two Cu(II) cations, building a linear chain along [001]. The chains are connected by 3-(pyridin-4-yl)-1H-pyrazol-1-ide anions, constructing a layer parallel to (101). The layers are assembled into a three-dimensional supramolecular network through C—H⋯π interactions. |
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