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Poly[dimethylammonium [(μ(2)-benzene-1,2-dicarboxylato-κ(2) O (1):O (3))[μ(2)-3-(pyridin-4-yl)-1H-pyrazol-1-ido-κ(2) N (1):N (3)]cuprate(II)]]
In the title complex, {(C(2)H(8)N)[Cu(C(8)H(4)O(4))(C(8)H(6)N(3))]}(n), there are two Cu(II) cations (each located on a centre of inversion), one benzene-1,2-dicarboxylate dianion, one 3-(pyridin-4-yl)-1H-pyrazol-1-ide anion and one dimethylammonium cation in the asymmetric unit. The dimethyla...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772430/ https://www.ncbi.nlm.nih.gov/pubmed/24046573 http://dx.doi.org/10.1107/S1600536813016334 |
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author | Na, Liu |
author_facet | Na, Liu |
author_sort | Na, Liu |
collection | PubMed |
description | In the title complex, {(C(2)H(8)N)[Cu(C(8)H(4)O(4))(C(8)H(6)N(3))]}(n), there are two Cu(II) cations (each located on a centre of inversion), one benzene-1,2-dicarboxylate dianion, one 3-(pyridin-4-yl)-1H-pyrazol-1-ide anion and one dimethylammonium cation in the asymmetric unit. The dimethylammonium cation was highly disordered and was treated with the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the crystallographic data takes into account the presence of the cation. Each Cu(II) cation exhibits a square-planar coordination geometry. A benzene-1,2-dicarboxylate dianion bridges two Cu(II) cations, building a linear chain along [001]. The chains are connected by 3-(pyridin-4-yl)-1H-pyrazol-1-ide anions, constructing a layer parallel to (101). The layers are assembled into a three-dimensional supramolecular network through C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3772430 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37724302013-09-17 Poly[dimethylammonium [(μ(2)-benzene-1,2-dicarboxylato-κ(2) O (1):O (3))[μ(2)-3-(pyridin-4-yl)-1H-pyrazol-1-ido-κ(2) N (1):N (3)]cuprate(II)]] Na, Liu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {(C(2)H(8)N)[Cu(C(8)H(4)O(4))(C(8)H(6)N(3))]}(n), there are two Cu(II) cations (each located on a centre of inversion), one benzene-1,2-dicarboxylate dianion, one 3-(pyridin-4-yl)-1H-pyrazol-1-ide anion and one dimethylammonium cation in the asymmetric unit. The dimethylammonium cation was highly disordered and was treated with the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the crystallographic data takes into account the presence of the cation. Each Cu(II) cation exhibits a square-planar coordination geometry. A benzene-1,2-dicarboxylate dianion bridges two Cu(II) cations, building a linear chain along [001]. The chains are connected by 3-(pyridin-4-yl)-1H-pyrazol-1-ide anions, constructing a layer parallel to (101). The layers are assembled into a three-dimensional supramolecular network through C—H⋯π interactions. International Union of Crystallography 2013-06-19 /pmc/articles/PMC3772430/ /pubmed/24046573 http://dx.doi.org/10.1107/S1600536813016334 Text en © Liu Na 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Na, Liu Poly[dimethylammonium [(μ(2)-benzene-1,2-dicarboxylato-κ(2) O (1):O (3))[μ(2)-3-(pyridin-4-yl)-1H-pyrazol-1-ido-κ(2) N (1):N (3)]cuprate(II)]] |
title | Poly[dimethylammonium [(μ(2)-benzene-1,2-dicarboxylato-κ(2)
O
(1):O
(3))[μ(2)-3-(pyridin-4-yl)-1H-pyrazol-1-ido-κ(2)
N
(1):N
(3)]cuprate(II)]] |
title_full | Poly[dimethylammonium [(μ(2)-benzene-1,2-dicarboxylato-κ(2)
O
(1):O
(3))[μ(2)-3-(pyridin-4-yl)-1H-pyrazol-1-ido-κ(2)
N
(1):N
(3)]cuprate(II)]] |
title_fullStr | Poly[dimethylammonium [(μ(2)-benzene-1,2-dicarboxylato-κ(2)
O
(1):O
(3))[μ(2)-3-(pyridin-4-yl)-1H-pyrazol-1-ido-κ(2)
N
(1):N
(3)]cuprate(II)]] |
title_full_unstemmed | Poly[dimethylammonium [(μ(2)-benzene-1,2-dicarboxylato-κ(2)
O
(1):O
(3))[μ(2)-3-(pyridin-4-yl)-1H-pyrazol-1-ido-κ(2)
N
(1):N
(3)]cuprate(II)]] |
title_short | Poly[dimethylammonium [(μ(2)-benzene-1,2-dicarboxylato-κ(2)
O
(1):O
(3))[μ(2)-3-(pyridin-4-yl)-1H-pyrazol-1-ido-κ(2)
N
(1):N
(3)]cuprate(II)]] |
title_sort | poly[dimethylammonium [(μ(2)-benzene-1,2-dicarboxylato-κ(2)
o
(1):o
(3))[μ(2)-3-(pyridin-4-yl)-1h-pyrazol-1-ido-κ(2)
n
(1):n
(3)]cuprate(ii)]] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772430/ https://www.ncbi.nlm.nih.gov/pubmed/24046573 http://dx.doi.org/10.1107/S1600536813016334 |
work_keys_str_mv | AT naliu polydimethylammoniumm2benzene12dicarboxylatok2o1o3m23pyridin4yl1hpyrazol1idok2n1n3cuprateii |