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Poly[di­methyl­ammonium [(μ(2)-benzene-1,2-di­carboxyl­ato-κ(2) O (1):O (3))[μ(2)-3-(pyri­din-4-yl)-1H-pyrazol-1-ido-κ(2) N (1):N (3)]cuprate(II)]]

In the title complex, {(C(2)H(8)N)[Cu(C(8)H(4)O(4))(C(8)H(6)N(3))]}(n), there are two Cu(II) cations (each located on a centre of inversion), one benzene-1,2-di­carboxyl­ate dianion, one 3-(pyridin-4-yl)-1H-pyrazol-1-ide anion and one di­methyl­ammonium cation in the asymmetric unit. The di­methyl­a...

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Autor principal: Na, Liu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772430/
https://www.ncbi.nlm.nih.gov/pubmed/24046573
http://dx.doi.org/10.1107/S1600536813016334
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author Na, Liu
author_facet Na, Liu
author_sort Na, Liu
collection PubMed
description In the title complex, {(C(2)H(8)N)[Cu(C(8)H(4)O(4))(C(8)H(6)N(3))]}(n), there are two Cu(II) cations (each located on a centre of inversion), one benzene-1,2-di­carboxyl­ate dianion, one 3-(pyridin-4-yl)-1H-pyrazol-1-ide anion and one di­methyl­ammonium cation in the asymmetric unit. The di­methyl­ammonium cation was highly disordered and was treated with the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the crystallographic data takes into account the presence of the cation. Each Cu(II) cation exhibits a square-planar coordination geometry. A benzene-1,2-di­carboxyl­ate dianion bridges two Cu(II) cations, building a linear chain along [001]. The chains are connected by 3-(pyridin-4-yl)-1H-pyrazol-1-ide anions, constructing a layer parallel to (101). The layers are assembled into a three-dimensional supra­molecular network through C—H⋯π inter­actions.
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spelling pubmed-37724302013-09-17 Poly[di­methyl­ammonium [(μ(2)-benzene-1,2-di­carboxyl­ato-κ(2) O (1):O (3))[μ(2)-3-(pyri­din-4-yl)-1H-pyrazol-1-ido-κ(2) N (1):N (3)]cuprate(II)]] Na, Liu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {(C(2)H(8)N)[Cu(C(8)H(4)O(4))(C(8)H(6)N(3))]}(n), there are two Cu(II) cations (each located on a centre of inversion), one benzene-1,2-di­carboxyl­ate dianion, one 3-(pyridin-4-yl)-1H-pyrazol-1-ide anion and one di­methyl­ammonium cation in the asymmetric unit. The di­methyl­ammonium cation was highly disordered and was treated with the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]; the crystallographic data takes into account the presence of the cation. Each Cu(II) cation exhibits a square-planar coordination geometry. A benzene-1,2-di­carboxyl­ate dianion bridges two Cu(II) cations, building a linear chain along [001]. The chains are connected by 3-(pyridin-4-yl)-1H-pyrazol-1-ide anions, constructing a layer parallel to (101). The layers are assembled into a three-dimensional supra­molecular network through C—H⋯π inter­actions. International Union of Crystallography 2013-06-19 /pmc/articles/PMC3772430/ /pubmed/24046573 http://dx.doi.org/10.1107/S1600536813016334 Text en © Liu Na 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Na, Liu
Poly[di­methyl­ammonium [(μ(2)-benzene-1,2-di­carboxyl­ato-κ(2) O (1):O (3))[μ(2)-3-(pyri­din-4-yl)-1H-pyrazol-1-ido-κ(2) N (1):N (3)]cuprate(II)]]
title Poly[di­methyl­ammonium [(μ(2)-benzene-1,2-di­carboxyl­ato-κ(2) O (1):O (3))[μ(2)-3-(pyri­din-4-yl)-1H-pyrazol-1-ido-κ(2) N (1):N (3)]cuprate(II)]]
title_full Poly[di­methyl­ammonium [(μ(2)-benzene-1,2-di­carboxyl­ato-κ(2) O (1):O (3))[μ(2)-3-(pyri­din-4-yl)-1H-pyrazol-1-ido-κ(2) N (1):N (3)]cuprate(II)]]
title_fullStr Poly[di­methyl­ammonium [(μ(2)-benzene-1,2-di­carboxyl­ato-κ(2) O (1):O (3))[μ(2)-3-(pyri­din-4-yl)-1H-pyrazol-1-ido-κ(2) N (1):N (3)]cuprate(II)]]
title_full_unstemmed Poly[di­methyl­ammonium [(μ(2)-benzene-1,2-di­carboxyl­ato-κ(2) O (1):O (3))[μ(2)-3-(pyri­din-4-yl)-1H-pyrazol-1-ido-κ(2) N (1):N (3)]cuprate(II)]]
title_short Poly[di­methyl­ammonium [(μ(2)-benzene-1,2-di­carboxyl­ato-κ(2) O (1):O (3))[μ(2)-3-(pyri­din-4-yl)-1H-pyrazol-1-ido-κ(2) N (1):N (3)]cuprate(II)]]
title_sort poly[di­methyl­ammonium [(μ(2)-benzene-1,2-di­carboxyl­ato-κ(2) o (1):o (3))[μ(2)-3-(pyri­din-4-yl)-1h-pyrazol-1-ido-κ(2) n (1):n (3)]cuprate(ii)]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772430/
https://www.ncbi.nlm.nih.gov/pubmed/24046573
http://dx.doi.org/10.1107/S1600536813016334
work_keys_str_mv AT naliu polydimethylammoniumm2benzene12dicarboxylatok2o1o3m23pyridin4yl1hpyrazol1idok2n1n3cuprateii