Chlorido[2,2′-[1,2-phenyl­enebis(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′]manganese(III) methanol monosolvate

In the title complex, [Mn(C(20)H(14)N(2)O(2))Cl]·CH(3)OH, the central Mn(III) atom displays a distorted square-pyramidal coordination by two N and two O atoms from the tetradentate 2,2′-[1,2-phenyl­enebis(nitrilo­methanylyl­idyne)]diphenolate ligand and one chloride ligand. The Mn(III) atom is 0.525...

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Autores principales: Lin, Hui, Wang, Jian-Gang, Shi, Hua-Tian, Chen, Qun, Zhang, Qian-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772432/
https://www.ncbi.nlm.nih.gov/pubmed/24046575
http://dx.doi.org/10.1107/S1600536813016450
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author Lin, Hui
Wang, Jian-Gang
Shi, Hua-Tian
Chen, Qun
Zhang, Qian-Feng
author_facet Lin, Hui
Wang, Jian-Gang
Shi, Hua-Tian
Chen, Qun
Zhang, Qian-Feng
author_sort Lin, Hui
collection PubMed
description In the title complex, [Mn(C(20)H(14)N(2)O(2))Cl]·CH(3)OH, the central Mn(III) atom displays a distorted square-pyramidal coordination by two N and two O atoms from the tetradentate 2,2′-[1,2-phenyl­enebis(nitrilo­methanylyl­idyne)]diphenolate ligand and one chloride ligand. The Mn(III) atom is 0.525 (4) Å out of the square basal N(2)O(2) least-squares plane. The complex mol­ecule is hydrogen bonded to the methanol solvent mol­ecule.
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spelling pubmed-37724322013-09-17 Chlorido[2,2′-[1,2-phenyl­enebis(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′]manganese(III) methanol monosolvate Lin, Hui Wang, Jian-Gang Shi, Hua-Tian Chen, Qun Zhang, Qian-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(20)H(14)N(2)O(2))Cl]·CH(3)OH, the central Mn(III) atom displays a distorted square-pyramidal coordination by two N and two O atoms from the tetradentate 2,2′-[1,2-phenyl­enebis(nitrilo­methanylyl­idyne)]diphenolate ligand and one chloride ligand. The Mn(III) atom is 0.525 (4) Å out of the square basal N(2)O(2) least-squares plane. The complex mol­ecule is hydrogen bonded to the methanol solvent mol­ecule. International Union of Crystallography 2013-06-19 /pmc/articles/PMC3772432/ /pubmed/24046575 http://dx.doi.org/10.1107/S1600536813016450 Text en © Lin et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lin, Hui
Wang, Jian-Gang
Shi, Hua-Tian
Chen, Qun
Zhang, Qian-Feng
Chlorido[2,2′-[1,2-phenyl­enebis(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′]manganese(III) methanol monosolvate
title Chlorido[2,2′-[1,2-phenyl­enebis(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′]manganese(III) methanol monosolvate
title_full Chlorido[2,2′-[1,2-phenyl­enebis(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′]manganese(III) methanol monosolvate
title_fullStr Chlorido[2,2′-[1,2-phenyl­enebis(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′]manganese(III) methanol monosolvate
title_full_unstemmed Chlorido[2,2′-[1,2-phenyl­enebis(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′]manganese(III) methanol monosolvate
title_short Chlorido[2,2′-[1,2-phenyl­enebis(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′]manganese(III) methanol monosolvate
title_sort chlorido[2,2′-[1,2-phenyl­enebis(nitrilo­methanylyl­idyne)]diphenolato-κ(4) o,n,n′,o′]manganese(iii) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772432/
https://www.ncbi.nlm.nih.gov/pubmed/24046575
http://dx.doi.org/10.1107/S1600536813016450
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