Bis{1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olato}copper(II)

The Cu(II) atom in the title compound, [Cu(C(16)H(10)ClN(2)O)(2)], is located on an inversion center and is tetra­coordinated by two N and two O atoms from two bidentate 1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, mol­ecules are lin...

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Detalles Bibliográficos
Autores principales: Benaouida, Mohamed Amine, Benosmane, Ali, Bouguerria, Hassiba, Bouaoud, Salah Eddine, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772433/
https://www.ncbi.nlm.nih.gov/pubmed/24046576
http://dx.doi.org/10.1107/S1600536813016681
Descripción
Sumario:The Cu(II) atom in the title compound, [Cu(C(16)H(10)ClN(2)O)(2)], is located on an inversion center and is tetra­coordinated by two N and two O atoms from two bidentate 1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, mol­ecules are linked via weak C—H⋯O and C—H⋯Cl hydrogen bonds, forming chains propagating along [010]. There are also π–π inter­actions present involving adjacent naphthalene rings [centroid–centroid distance = 3.661 (13) Å].

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