Bis{1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olato}copper(II)

The Cu(II) atom in the title compound, [Cu(C(16)H(10)ClN(2)O)(2)], is located on an inversion center and is tetra­coordinated by two N and two O atoms from two bidentate 1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, mol­ecules are lin...

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Autores principales: Benaouida, Mohamed Amine, Benosmane, Ali, Bouguerria, Hassiba, Bouaoud, Salah Eddine, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772433/
https://www.ncbi.nlm.nih.gov/pubmed/24046576
http://dx.doi.org/10.1107/S1600536813016681
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author Benaouida, Mohamed Amine
Benosmane, Ali
Bouguerria, Hassiba
Bouaoud, Salah Eddine
Merazig, Hocine
author_facet Benaouida, Mohamed Amine
Benosmane, Ali
Bouguerria, Hassiba
Bouaoud, Salah Eddine
Merazig, Hocine
author_sort Benaouida, Mohamed Amine
collection PubMed
description The Cu(II) atom in the title compound, [Cu(C(16)H(10)ClN(2)O)(2)], is located on an inversion center and is tetra­coordinated by two N and two O atoms from two bidentate 1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, mol­ecules are linked via weak C—H⋯O and C—H⋯Cl hydrogen bonds, forming chains propagating along [010]. There are also π–π inter­actions present involving adjacent naphthalene rings [centroid–centroid distance = 3.661 (13) Å].
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spelling pubmed-37724332013-09-17 Bis{1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olato}copper(II) Benaouida, Mohamed Amine Benosmane, Ali Bouguerria, Hassiba Bouaoud, Salah Eddine Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title compound, [Cu(C(16)H(10)ClN(2)O)(2)], is located on an inversion center and is tetra­coordinated by two N and two O atoms from two bidentate 1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, mol­ecules are linked via weak C—H⋯O and C—H⋯Cl hydrogen bonds, forming chains propagating along [010]. There are also π–π inter­actions present involving adjacent naphthalene rings [centroid–centroid distance = 3.661 (13) Å]. International Union of Crystallography 2013-06-22 /pmc/articles/PMC3772433/ /pubmed/24046576 http://dx.doi.org/10.1107/S1600536813016681 Text en © Benaouida et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Benaouida, Mohamed Amine
Benosmane, Ali
Bouguerria, Hassiba
Bouaoud, Salah Eddine
Merazig, Hocine
Bis{1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olato}copper(II)
title Bis{1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olato}copper(II)
title_full Bis{1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olato}copper(II)
title_fullStr Bis{1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olato}copper(II)
title_full_unstemmed Bis{1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olato}copper(II)
title_short Bis{1-[(E)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olato}copper(II)
title_sort bis{1-[(e)-(2-chloro­phen­yl)diazen­yl]naphthalen-2-olato}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772433/
https://www.ncbi.nlm.nih.gov/pubmed/24046576
http://dx.doi.org/10.1107/S1600536813016681
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