Cargando…
Poly[tetrabutylammonium [chloridohexamethyl-μ(3)-sulfato-distannate(IV)]]
In the structure of the title coordination polymer, {(C(16)H(36)N)[Sn(2)(CH(3))(6)Cl(SO(4))]}(n), the two independent Sn(IV) atoms are coordinated in a trigonal–bipyramidal manner by three methyl groups in the equatorial plane and in the axial positions by either two O atoms of bridging SO(4) (2−) a...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772434/ https://www.ncbi.nlm.nih.gov/pubmed/24046577 http://dx.doi.org/10.1107/S1600536813016723 |
Sumario: | In the structure of the title coordination polymer, {(C(16)H(36)N)[Sn(2)(CH(3))(6)Cl(SO(4))]}(n), the two independent Sn(IV) atoms are coordinated in a trigonal–bipyramidal manner by three methyl groups in the equatorial plane and in the axial positions by either two O atoms of bridging SO(4) (2−) anions or by a Cl atom and one O atom of a bridging SO(4) (2−) anion, respectively. The [Sn(2)(CH(3))(6)Cl(SO(4))](−) anion forms an infinite zigzag chain parallel to the c axis. The cations are situated between these chains. Two of the four butyl groups of the cation are partially disordered over two sets of sites with site occupancies of 0.79 (2):0.21 (2) and 0.75 (2):0.25 (2), respectively. Weak C—H⋯O hydrogen-bonding interactions help to consolidate the crystal packing. |
---|