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Poly[tetra­butyl­ammonium [chlorido­hexa­methyl-μ(3)-sulfato-distannate(IV)]]

In the structure of the title coordination polymer, {(C(16)H(36)N)[Sn(2)(CH(3))(6)Cl(SO(4))]}(n), the two independent Sn(IV) atoms are coordinated in a trigonal–bipyramidal manner by three methyl groups in the equatorial plane and in the axial positions by either two O atoms of bridging SO(4) (2−) a...

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Detalles Bibliográficos
Autores principales: Diop, Tidiane, van der Lee, Arie, Sidibé, Mamadou
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772434/
https://www.ncbi.nlm.nih.gov/pubmed/24046577
http://dx.doi.org/10.1107/S1600536813016723
Descripción
Sumario:In the structure of the title coordination polymer, {(C(16)H(36)N)[Sn(2)(CH(3))(6)Cl(SO(4))]}(n), the two independent Sn(IV) atoms are coordinated in a trigonal–bipyramidal manner by three methyl groups in the equatorial plane and in the axial positions by either two O atoms of bridging SO(4) (2−) anions or by a Cl atom and one O atom of a bridging SO(4) (2−) anion, respectively. The [Sn(2)(CH(3))(6)Cl(SO(4))](−) anion forms an infinite zigzag chain parallel to the c axis. The cations are situated between these chains. Two of the four butyl groups of the cation are partially disordered over two sets of sites with site occupancies of 0.79 (2):0.21 (2) and 0.75 (2):0.25 (2), respectively. Weak C—H⋯O hydrogen-bonding inter­actions help to consolidate the crystal packing.