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Poly[tetrabutylammonium [chloridohexamethyl-μ(3)-sulfato-distannate(IV)]]
In the structure of the title coordination polymer, {(C(16)H(36)N)[Sn(2)(CH(3))(6)Cl(SO(4))]}(n), the two independent Sn(IV) atoms are coordinated in a trigonal–bipyramidal manner by three methyl groups in the equatorial plane and in the axial positions by either two O atoms of bridging SO(4) (2−) a...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772434/ https://www.ncbi.nlm.nih.gov/pubmed/24046577 http://dx.doi.org/10.1107/S1600536813016723 |
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author | Diop, Tidiane van der Lee, Arie Sidibé, Mamadou |
author_facet | Diop, Tidiane van der Lee, Arie Sidibé, Mamadou |
author_sort | Diop, Tidiane |
collection | PubMed |
description | In the structure of the title coordination polymer, {(C(16)H(36)N)[Sn(2)(CH(3))(6)Cl(SO(4))]}(n), the two independent Sn(IV) atoms are coordinated in a trigonal–bipyramidal manner by three methyl groups in the equatorial plane and in the axial positions by either two O atoms of bridging SO(4) (2−) anions or by a Cl atom and one O atom of a bridging SO(4) (2−) anion, respectively. The [Sn(2)(CH(3))(6)Cl(SO(4))](−) anion forms an infinite zigzag chain parallel to the c axis. The cations are situated between these chains. Two of the four butyl groups of the cation are partially disordered over two sets of sites with site occupancies of 0.79 (2):0.21 (2) and 0.75 (2):0.25 (2), respectively. Weak C—H⋯O hydrogen-bonding interactions help to consolidate the crystal packing. |
format | Online Article Text |
id | pubmed-3772434 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37724342013-09-17 Poly[tetrabutylammonium [chloridohexamethyl-μ(3)-sulfato-distannate(IV)]] Diop, Tidiane van der Lee, Arie Sidibé, Mamadou Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title coordination polymer, {(C(16)H(36)N)[Sn(2)(CH(3))(6)Cl(SO(4))]}(n), the two independent Sn(IV) atoms are coordinated in a trigonal–bipyramidal manner by three methyl groups in the equatorial plane and in the axial positions by either two O atoms of bridging SO(4) (2−) anions or by a Cl atom and one O atom of a bridging SO(4) (2−) anion, respectively. The [Sn(2)(CH(3))(6)Cl(SO(4))](−) anion forms an infinite zigzag chain parallel to the c axis. The cations are situated between these chains. Two of the four butyl groups of the cation are partially disordered over two sets of sites with site occupancies of 0.79 (2):0.21 (2) and 0.75 (2):0.25 (2), respectively. Weak C—H⋯O hydrogen-bonding interactions help to consolidate the crystal packing. International Union of Crystallography 2013-06-22 /pmc/articles/PMC3772434/ /pubmed/24046577 http://dx.doi.org/10.1107/S1600536813016723 Text en © Diop et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Diop, Tidiane van der Lee, Arie Sidibé, Mamadou Poly[tetrabutylammonium [chloridohexamethyl-μ(3)-sulfato-distannate(IV)]] |
title | Poly[tetrabutylammonium [chloridohexamethyl-μ(3)-sulfato-distannate(IV)]] |
title_full | Poly[tetrabutylammonium [chloridohexamethyl-μ(3)-sulfato-distannate(IV)]] |
title_fullStr | Poly[tetrabutylammonium [chloridohexamethyl-μ(3)-sulfato-distannate(IV)]] |
title_full_unstemmed | Poly[tetrabutylammonium [chloridohexamethyl-μ(3)-sulfato-distannate(IV)]] |
title_short | Poly[tetrabutylammonium [chloridohexamethyl-μ(3)-sulfato-distannate(IV)]] |
title_sort | poly[tetrabutylammonium [chloridohexamethyl-μ(3)-sulfato-distannate(iv)]] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772434/ https://www.ncbi.nlm.nih.gov/pubmed/24046577 http://dx.doi.org/10.1107/S1600536813016723 |
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