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Poly[tetra­butyl­ammonium [chlorido­hexa­methyl-μ(3)-sulfato-distannate(IV)]]

In the structure of the title coordination polymer, {(C(16)H(36)N)[Sn(2)(CH(3))(6)Cl(SO(4))]}(n), the two independent Sn(IV) atoms are coordinated in a trigonal–bipyramidal manner by three methyl groups in the equatorial plane and in the axial positions by either two O atoms of bridging SO(4) (2−) a...

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Autores principales: Diop, Tidiane, van der Lee, Arie, Sidibé, Mamadou
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772434/
https://www.ncbi.nlm.nih.gov/pubmed/24046577
http://dx.doi.org/10.1107/S1600536813016723
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author Diop, Tidiane
van der Lee, Arie
Sidibé, Mamadou
author_facet Diop, Tidiane
van der Lee, Arie
Sidibé, Mamadou
author_sort Diop, Tidiane
collection PubMed
description In the structure of the title coordination polymer, {(C(16)H(36)N)[Sn(2)(CH(3))(6)Cl(SO(4))]}(n), the two independent Sn(IV) atoms are coordinated in a trigonal–bipyramidal manner by three methyl groups in the equatorial plane and in the axial positions by either two O atoms of bridging SO(4) (2−) anions or by a Cl atom and one O atom of a bridging SO(4) (2−) anion, respectively. The [Sn(2)(CH(3))(6)Cl(SO(4))](−) anion forms an infinite zigzag chain parallel to the c axis. The cations are situated between these chains. Two of the four butyl groups of the cation are partially disordered over two sets of sites with site occupancies of 0.79 (2):0.21 (2) and 0.75 (2):0.25 (2), respectively. Weak C—H⋯O hydrogen-bonding inter­actions help to consolidate the crystal packing.
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spelling pubmed-37724342013-09-17 Poly[tetra­butyl­ammonium [chlorido­hexa­methyl-μ(3)-sulfato-distannate(IV)]] Diop, Tidiane van der Lee, Arie Sidibé, Mamadou Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title coordination polymer, {(C(16)H(36)N)[Sn(2)(CH(3))(6)Cl(SO(4))]}(n), the two independent Sn(IV) atoms are coordinated in a trigonal–bipyramidal manner by three methyl groups in the equatorial plane and in the axial positions by either two O atoms of bridging SO(4) (2−) anions or by a Cl atom and one O atom of a bridging SO(4) (2−) anion, respectively. The [Sn(2)(CH(3))(6)Cl(SO(4))](−) anion forms an infinite zigzag chain parallel to the c axis. The cations are situated between these chains. Two of the four butyl groups of the cation are partially disordered over two sets of sites with site occupancies of 0.79 (2):0.21 (2) and 0.75 (2):0.25 (2), respectively. Weak C—H⋯O hydrogen-bonding inter­actions help to consolidate the crystal packing. International Union of Crystallography 2013-06-22 /pmc/articles/PMC3772434/ /pubmed/24046577 http://dx.doi.org/10.1107/S1600536813016723 Text en © Diop et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Diop, Tidiane
van der Lee, Arie
Sidibé, Mamadou
Poly[tetra­butyl­ammonium [chlorido­hexa­methyl-μ(3)-sulfato-distannate(IV)]]
title Poly[tetra­butyl­ammonium [chlorido­hexa­methyl-μ(3)-sulfato-distannate(IV)]]
title_full Poly[tetra­butyl­ammonium [chlorido­hexa­methyl-μ(3)-sulfato-distannate(IV)]]
title_fullStr Poly[tetra­butyl­ammonium [chlorido­hexa­methyl-μ(3)-sulfato-distannate(IV)]]
title_full_unstemmed Poly[tetra­butyl­ammonium [chlorido­hexa­methyl-μ(3)-sulfato-distannate(IV)]]
title_short Poly[tetra­butyl­ammonium [chlorido­hexa­methyl-μ(3)-sulfato-distannate(IV)]]
title_sort poly[tetra­butyl­ammonium [chlorido­hexa­methyl-μ(3)-sulfato-distannate(iv)]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772434/
https://www.ncbi.nlm.nih.gov/pubmed/24046577
http://dx.doi.org/10.1107/S1600536813016723
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