cis-Bis(O-methyl­dithio­carbonato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II)

In the title compound, [Ru(CH(3)OCS(2))(2)(C(18)H(15)P)(2)], the Ru(II) atom is in a distorted octa­hedral coordination by two xanthate anions (CH(3)OCS(2)) and two tri­phenyl­phosphane (PPh(3)) ligands. Both bidentate xanthate ligands coordinate the Ru(II) atom with two slightly different Ru—S bond...

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Detalles Bibliográficos
Autores principales: Valerio-Cárdenas, Cintya, Hernández-Ortega, Simón, Reyes-Martínez, Reyna, Morales-Morales, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772435/
https://www.ncbi.nlm.nih.gov/pubmed/24046578
http://dx.doi.org/10.1107/S1600536813016735
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author Valerio-Cárdenas, Cintya
Hernández-Ortega, Simón
Reyes-Martínez, Reyna
Morales-Morales, David
author_facet Valerio-Cárdenas, Cintya
Hernández-Ortega, Simón
Reyes-Martínez, Reyna
Morales-Morales, David
author_sort Valerio-Cárdenas, Cintya
collection PubMed
description In the title compound, [Ru(CH(3)OCS(2))(2)(C(18)H(15)P)(2)], the Ru(II) atom is in a distorted octa­hedral coordination by two xanthate anions (CH(3)OCS(2)) and two tri­phenyl­phosphane (PPh(3)) ligands. Both bidentate xanthate ligands coordinate the Ru(II) atom with two slightly different Ru—S bond lengths but with virtually equal bite angles [71.57 (4) and 71.58 (3)°]. The packing of the complexes is assured by C—H⋯O and C—H⋯π inter­actions.
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spelling pubmed-37724352013-09-17 cis-Bis(O-methyl­dithio­carbonato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II) Valerio-Cárdenas, Cintya Hernández-Ortega, Simón Reyes-Martínez, Reyna Morales-Morales, David Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ru(CH(3)OCS(2))(2)(C(18)H(15)P)(2)], the Ru(II) atom is in a distorted octa­hedral coordination by two xanthate anions (CH(3)OCS(2)) and two tri­phenyl­phosphane (PPh(3)) ligands. Both bidentate xanthate ligands coordinate the Ru(II) atom with two slightly different Ru—S bond lengths but with virtually equal bite angles [71.57 (4) and 71.58 (3)°]. The packing of the complexes is assured by C—H⋯O and C—H⋯π inter­actions. International Union of Crystallography 2013-06-22 /pmc/articles/PMC3772435/ /pubmed/24046578 http://dx.doi.org/10.1107/S1600536813016735 Text en © Valerio-Cárdenas et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Valerio-Cárdenas, Cintya
Hernández-Ortega, Simón
Reyes-Martínez, Reyna
Morales-Morales, David
cis-Bis(O-methyl­dithio­carbonato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II)
title cis-Bis(O-methyl­dithio­carbonato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II)
title_full cis-Bis(O-methyl­dithio­carbonato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II)
title_fullStr cis-Bis(O-methyl­dithio­carbonato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II)
title_full_unstemmed cis-Bis(O-methyl­dithio­carbonato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II)
title_short cis-Bis(O-methyl­dithio­carbonato-κ(2) S,S′)bis­(tri­phenyl­phosphane-κP)ruthenium(II)
title_sort cis-bis(o-methyl­dithio­carbonato-κ(2) s,s′)bis­(tri­phenyl­phosphane-κp)ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772435/
https://www.ncbi.nlm.nih.gov/pubmed/24046578
http://dx.doi.org/10.1107/S1600536813016735
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