trans-Diamminedichloridobis(1H-imidazole-κN (3))nickel(II)

The whole mol­ecule of the title compound, [NiCl(2)(C(3)H(4)N(2))(2)(NH(3))(2)], is generated by inversion symmetry. The Ni(II) ion, which is located on an inversion center, has a distorted octa­hedral coordination environment and is surrounded by two ammine N atoms and two Cl atoms in the equatoria...

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Autores principales: Kannan, Piskala Subburaman, Ganeshraja, Ayyakannu Sundaram, Rajkumar, Kanniah, Anbalagan, Krishnamoorthy, SubbiahPandi, Arunachalatheva
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772436/
https://www.ncbi.nlm.nih.gov/pubmed/24046579
http://dx.doi.org/10.1107/S1600536813016747
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author Kannan, Piskala Subburaman
Ganeshraja, Ayyakannu Sundaram
Rajkumar, Kanniah
Anbalagan, Krishnamoorthy
SubbiahPandi, Arunachalatheva
author_facet Kannan, Piskala Subburaman
Ganeshraja, Ayyakannu Sundaram
Rajkumar, Kanniah
Anbalagan, Krishnamoorthy
SubbiahPandi, Arunachalatheva
author_sort Kannan, Piskala Subburaman
collection PubMed
description The whole mol­ecule of the title compound, [NiCl(2)(C(3)H(4)N(2))(2)(NH(3))(2)], is generated by inversion symmetry. The Ni(II) ion, which is located on an inversion center, has a distorted octa­hedral coordination environment and is surrounded by two ammine N atoms and two Cl atoms in the equatorial plane, with two N atoms of two imidazole groups occupying the axial positions. The imidazole ring makes a dihedral angle of 81.78 (18)° with the Ni/N/Cl equatorial plane. In the crystal, mol­ecules are linked via N—H⋯Cl hydrogen bonds and C—H⋯π inter­actions, forming a three-dimensional network.
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spelling pubmed-37724362013-09-17 trans-Diamminedichloridobis(1H-imidazole-κN (3))nickel(II) Kannan, Piskala Subburaman Ganeshraja, Ayyakannu Sundaram Rajkumar, Kanniah Anbalagan, Krishnamoorthy SubbiahPandi, Arunachalatheva Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The whole mol­ecule of the title compound, [NiCl(2)(C(3)H(4)N(2))(2)(NH(3))(2)], is generated by inversion symmetry. The Ni(II) ion, which is located on an inversion center, has a distorted octa­hedral coordination environment and is surrounded by two ammine N atoms and two Cl atoms in the equatorial plane, with two N atoms of two imidazole groups occupying the axial positions. The imidazole ring makes a dihedral angle of 81.78 (18)° with the Ni/N/Cl equatorial plane. In the crystal, mol­ecules are linked via N—H⋯Cl hydrogen bonds and C—H⋯π inter­actions, forming a three-dimensional network. International Union of Crystallography 2013-06-22 /pmc/articles/PMC3772436/ /pubmed/24046579 http://dx.doi.org/10.1107/S1600536813016747 Text en © Kannan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kannan, Piskala Subburaman
Ganeshraja, Ayyakannu Sundaram
Rajkumar, Kanniah
Anbalagan, Krishnamoorthy
SubbiahPandi, Arunachalatheva
trans-Diamminedichloridobis(1H-imidazole-κN (3))nickel(II)
title trans-Diamminedichloridobis(1H-imidazole-κN (3))nickel(II)
title_full trans-Diamminedichloridobis(1H-imidazole-κN (3))nickel(II)
title_fullStr trans-Diamminedichloridobis(1H-imidazole-κN (3))nickel(II)
title_full_unstemmed trans-Diamminedichloridobis(1H-imidazole-κN (3))nickel(II)
title_short trans-Diamminedichloridobis(1H-imidazole-κN (3))nickel(II)
title_sort trans-diamminedichloridobis(1h-imidazole-κn (3))nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772436/
https://www.ncbi.nlm.nih.gov/pubmed/24046579
http://dx.doi.org/10.1107/S1600536813016747
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AT anbalagankrishnamoorthy transdiamminedichloridobis1himidazolekn3nickelii
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