catena-Poly[di-μ(3)-bromido-bis­[(1-ethyl-1H-imidazole-κN (3))disilver(I)]]

The asymmetric unit of the title coordination complex, [Ag(2)Br(2)(C(5)H(8)N(2))(2)](n), comprises a monodentate 1-ethyl­imida­zole ligand, an Ag(+) cation and a μ(3)-bridging Br(−) anion, giving a distorted tetra­hedral AgNBr(3) stereochemistry about the Ag(+) cation [Ag—N = 2.247 (2) Å and Ag—Br =...

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Detalles Bibliográficos
Autores principales: Wang, Zhiguo, Bian, Qingquan, Guo, Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772437/
https://www.ncbi.nlm.nih.gov/pubmed/24046580
http://dx.doi.org/10.1107/S1600536813016875
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author Wang, Zhiguo
Bian, Qingquan
Guo, Ying
author_facet Wang, Zhiguo
Bian, Qingquan
Guo, Ying
author_sort Wang, Zhiguo
collection PubMed
description The asymmetric unit of the title coordination complex, [Ag(2)Br(2)(C(5)H(8)N(2))(2)](n), comprises a monodentate 1-ethyl­imida­zole ligand, an Ag(+) cation and a μ(3)-bridging Br(−) anion, giving a distorted tetra­hedral AgNBr(3) stereochemistry about the Ag(+) cation [Ag—N = 2.247 (2) Å and Ag—Br = 2.7372 (4)–2.7523 (4) Å]. Two bridging bromide anions generate the dimeric [Ag(2)Br(2)(C(5)H(8)N)(2)] repeat unit [Ag⋯Ag = 3.0028 (5) Å], while a third Br(−) anion links the units through corner sharing in an inversion-related Ag(2)Br(2) association [Ag⋯Ag = 3.0407 (4) Å], generating a one-dimensional ribbon step-polymer structure, extending along the c axis.
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spelling pubmed-37724372013-09-17 catena-Poly[di-μ(3)-bromido-bis­[(1-ethyl-1H-imidazole-κN (3))disilver(I)]] Wang, Zhiguo Bian, Qingquan Guo, Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title coordination complex, [Ag(2)Br(2)(C(5)H(8)N(2))(2)](n), comprises a monodentate 1-ethyl­imida­zole ligand, an Ag(+) cation and a μ(3)-bridging Br(−) anion, giving a distorted tetra­hedral AgNBr(3) stereochemistry about the Ag(+) cation [Ag—N = 2.247 (2) Å and Ag—Br = 2.7372 (4)–2.7523 (4) Å]. Two bridging bromide anions generate the dimeric [Ag(2)Br(2)(C(5)H(8)N)(2)] repeat unit [Ag⋯Ag = 3.0028 (5) Å], while a third Br(−) anion links the units through corner sharing in an inversion-related Ag(2)Br(2) association [Ag⋯Ag = 3.0407 (4) Å], generating a one-dimensional ribbon step-polymer structure, extending along the c axis. International Union of Crystallography 2013-06-22 /pmc/articles/PMC3772437/ /pubmed/24046580 http://dx.doi.org/10.1107/S1600536813016875 Text en © Wang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Zhiguo
Bian, Qingquan
Guo, Ying
catena-Poly[di-μ(3)-bromido-bis­[(1-ethyl-1H-imidazole-κN (3))disilver(I)]]
title catena-Poly[di-μ(3)-bromido-bis­[(1-ethyl-1H-imidazole-κN (3))disilver(I)]]
title_full catena-Poly[di-μ(3)-bromido-bis­[(1-ethyl-1H-imidazole-κN (3))disilver(I)]]
title_fullStr catena-Poly[di-μ(3)-bromido-bis­[(1-ethyl-1H-imidazole-κN (3))disilver(I)]]
title_full_unstemmed catena-Poly[di-μ(3)-bromido-bis­[(1-ethyl-1H-imidazole-κN (3))disilver(I)]]
title_short catena-Poly[di-μ(3)-bromido-bis­[(1-ethyl-1H-imidazole-κN (3))disilver(I)]]
title_sort catena-poly[di-μ(3)-bromido-bis­[(1-ethyl-1h-imidazole-κn (3))disilver(i)]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772437/
https://www.ncbi.nlm.nih.gov/pubmed/24046580
http://dx.doi.org/10.1107/S1600536813016875
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