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Bis{2-[(5-hy­droxy­pent­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II)

In the title compound, [Cu(C(12)H(16)NO(2))(2)], the Cu(II) ion, located on a center of inversion, is coordinated by two singly deprotonated Schiff base ligands derived from condensation of salicyldehyde and 1-amino­pentan-5-ol. The imino N and phenol O atoms from both ligands offer a square-planar...

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Autores principales: Modak, Ritwik, Patra, Santu, Mandal, Senjuti, Sikdar, Yeasin, Goswami, Sanchita
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772438/
https://www.ncbi.nlm.nih.gov/pubmed/24046581
http://dx.doi.org/10.1107/S1600536813016802
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author Modak, Ritwik
Patra, Santu
Mandal, Senjuti
Sikdar, Yeasin
Goswami, Sanchita
author_facet Modak, Ritwik
Patra, Santu
Mandal, Senjuti
Sikdar, Yeasin
Goswami, Sanchita
author_sort Modak, Ritwik
collection PubMed
description In the title compound, [Cu(C(12)H(16)NO(2))(2)], the Cu(II) ion, located on a center of inversion, is coordinated by two singly deprotonated Schiff base ligands derived from condensation of salicyldehyde and 1-amino­pentan-5-ol. The imino N and phenol O atoms from both ligands offer a square-planar arrangement around the metal ion. The Cu—N and Cu—O bond lengths are 2.0146 (15) and 1.8870 (12) Å, respectively. Since the Cu—O and Cu—N bond lengths are different, it can be concluded that the resulting geometry of the complex is distorted. The aliphatic –OH group of the ligand is not coordinated and points away from the metal coordination zone and actively participates in hydrogen bonding connecting two other units and thus stabilizing the crystal lattice. This results in a two-dimensional extended array parallel to (201).
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spelling pubmed-37724382013-09-17 Bis{2-[(5-hy­droxy­pent­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II) Modak, Ritwik Patra, Santu Mandal, Senjuti Sikdar, Yeasin Goswami, Sanchita Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(12)H(16)NO(2))(2)], the Cu(II) ion, located on a center of inversion, is coordinated by two singly deprotonated Schiff base ligands derived from condensation of salicyldehyde and 1-amino­pentan-5-ol. The imino N and phenol O atoms from both ligands offer a square-planar arrangement around the metal ion. The Cu—N and Cu—O bond lengths are 2.0146 (15) and 1.8870 (12) Å, respectively. Since the Cu—O and Cu—N bond lengths are different, it can be concluded that the resulting geometry of the complex is distorted. The aliphatic –OH group of the ligand is not coordinated and points away from the metal coordination zone and actively participates in hydrogen bonding connecting two other units and thus stabilizing the crystal lattice. This results in a two-dimensional extended array parallel to (201). International Union of Crystallography 2013-06-26 /pmc/articles/PMC3772438/ /pubmed/24046581 http://dx.doi.org/10.1107/S1600536813016802 Text en © Modak et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Modak, Ritwik
Patra, Santu
Mandal, Senjuti
Sikdar, Yeasin
Goswami, Sanchita
Bis{2-[(5-hy­droxy­pent­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II)
title Bis{2-[(5-hy­droxy­pent­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II)
title_full Bis{2-[(5-hy­droxy­pent­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II)
title_fullStr Bis{2-[(5-hy­droxy­pent­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II)
title_full_unstemmed Bis{2-[(5-hy­droxy­pent­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II)
title_short Bis{2-[(5-hy­droxy­pent­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II)
title_sort bis{2-[(5-hy­droxy­pent­yl)imino­meth­yl]phenolato-κ(2) n,o (1)}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772438/
https://www.ncbi.nlm.nih.gov/pubmed/24046581
http://dx.doi.org/10.1107/S1600536813016802
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