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Bis{2-[(5-hydroxypentyl)iminomethyl]phenolato-κ(2) N,O (1)}copper(II)
In the title compound, [Cu(C(12)H(16)NO(2))(2)], the Cu(II) ion, located on a center of inversion, is coordinated by two singly deprotonated Schiff base ligands derived from condensation of salicyldehyde and 1-aminopentan-5-ol. The imino N and phenol O atoms from both ligands offer a square-planar...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772438/ https://www.ncbi.nlm.nih.gov/pubmed/24046581 http://dx.doi.org/10.1107/S1600536813016802 |
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author | Modak, Ritwik Patra, Santu Mandal, Senjuti Sikdar, Yeasin Goswami, Sanchita |
author_facet | Modak, Ritwik Patra, Santu Mandal, Senjuti Sikdar, Yeasin Goswami, Sanchita |
author_sort | Modak, Ritwik |
collection | PubMed |
description | In the title compound, [Cu(C(12)H(16)NO(2))(2)], the Cu(II) ion, located on a center of inversion, is coordinated by two singly deprotonated Schiff base ligands derived from condensation of salicyldehyde and 1-aminopentan-5-ol. The imino N and phenol O atoms from both ligands offer a square-planar arrangement around the metal ion. The Cu—N and Cu—O bond lengths are 2.0146 (15) and 1.8870 (12) Å, respectively. Since the Cu—O and Cu—N bond lengths are different, it can be concluded that the resulting geometry of the complex is distorted. The aliphatic –OH group of the ligand is not coordinated and points away from the metal coordination zone and actively participates in hydrogen bonding connecting two other units and thus stabilizing the crystal lattice. This results in a two-dimensional extended array parallel to (201). |
format | Online Article Text |
id | pubmed-3772438 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37724382013-09-17 Bis{2-[(5-hydroxypentyl)iminomethyl]phenolato-κ(2) N,O (1)}copper(II) Modak, Ritwik Patra, Santu Mandal, Senjuti Sikdar, Yeasin Goswami, Sanchita Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(12)H(16)NO(2))(2)], the Cu(II) ion, located on a center of inversion, is coordinated by two singly deprotonated Schiff base ligands derived from condensation of salicyldehyde and 1-aminopentan-5-ol. The imino N and phenol O atoms from both ligands offer a square-planar arrangement around the metal ion. The Cu—N and Cu—O bond lengths are 2.0146 (15) and 1.8870 (12) Å, respectively. Since the Cu—O and Cu—N bond lengths are different, it can be concluded that the resulting geometry of the complex is distorted. The aliphatic –OH group of the ligand is not coordinated and points away from the metal coordination zone and actively participates in hydrogen bonding connecting two other units and thus stabilizing the crystal lattice. This results in a two-dimensional extended array parallel to (201). International Union of Crystallography 2013-06-26 /pmc/articles/PMC3772438/ /pubmed/24046581 http://dx.doi.org/10.1107/S1600536813016802 Text en © Modak et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Modak, Ritwik Patra, Santu Mandal, Senjuti Sikdar, Yeasin Goswami, Sanchita Bis{2-[(5-hydroxypentyl)iminomethyl]phenolato-κ(2) N,O (1)}copper(II) |
title | Bis{2-[(5-hydroxypentyl)iminomethyl]phenolato-κ(2)
N,O
(1)}copper(II) |
title_full | Bis{2-[(5-hydroxypentyl)iminomethyl]phenolato-κ(2)
N,O
(1)}copper(II) |
title_fullStr | Bis{2-[(5-hydroxypentyl)iminomethyl]phenolato-κ(2)
N,O
(1)}copper(II) |
title_full_unstemmed | Bis{2-[(5-hydroxypentyl)iminomethyl]phenolato-κ(2)
N,O
(1)}copper(II) |
title_short | Bis{2-[(5-hydroxypentyl)iminomethyl]phenolato-κ(2)
N,O
(1)}copper(II) |
title_sort | bis{2-[(5-hydroxypentyl)iminomethyl]phenolato-κ(2)
n,o
(1)}copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772438/ https://www.ncbi.nlm.nih.gov/pubmed/24046581 http://dx.doi.org/10.1107/S1600536813016802 |
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