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catena-Poly[[silver(I)-μ-N-(pyridin-3-ylmeth­yl)pyridine-2-amine-κ(2) N:N′] tri­fluoro­methane­sulfonate]

In the asymmetric unit of the title polymeric complex, {[Ag(C(11)H(11)N(3))](CF(3)SO(3))}(n), there are two Ag(I) atoms, two N-(pyridin-3-ylmeth­yl)pyridine-2-amine ligands (A and B) and two CF(3)SO(3) (−) anions. One Ag(I) atom is coordinated by two pyridine N atoms from two symmetry-related A liga...

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Autores principales: Moon, Suk-Hee, Park, Ki-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772439/
https://www.ncbi.nlm.nih.gov/pubmed/24046582
http://dx.doi.org/10.1107/S1600536813016309
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author Moon, Suk-Hee
Park, Ki-Min
author_facet Moon, Suk-Hee
Park, Ki-Min
author_sort Moon, Suk-Hee
collection PubMed
description In the asymmetric unit of the title polymeric complex, {[Ag(C(11)H(11)N(3))](CF(3)SO(3))}(n), there are two Ag(I) atoms, two N-(pyridin-3-ylmeth­yl)pyridine-2-amine ligands (A and B) and two CF(3)SO(3) (−) anions. One Ag(I) atom is coordinated by two pyridine N atoms from two symmetry-related A ligands in a geometry slightly distorted from linear [N—Ag—N = 173.2 (3)°], forming a left-handed helical chain, while the other Ag(I) atom is coordinated by two pyridine N atoms from two symmetry-related B ligands in a bent arrangement [N—Ag—N = 157.1 (3)°], forming a right-handed helical chain. Both helical chains have the same pitch length [10.4007 (7) Å], propagate along the b-axis direction and are alternately arranged via Ag⋯Ag [3.0897 (12) Å] and π–π stacking inter­actions [centroid–centroid distances = 3.564 (7) and 3.518 (6) Å], resulting in the formation of a two-dimensional supra­molecular network extending parallel to the ab plane. Inter­molecular N—H⋯O, C—H⋯O and C—H⋯F hydrogen-bonding inter­actions occur between the helical chains and the anions.
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spelling pubmed-37724392013-09-17 catena-Poly[[silver(I)-μ-N-(pyridin-3-ylmeth­yl)pyridine-2-amine-κ(2) N:N′] tri­fluoro­methane­sulfonate] Moon, Suk-Hee Park, Ki-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the asymmetric unit of the title polymeric complex, {[Ag(C(11)H(11)N(3))](CF(3)SO(3))}(n), there are two Ag(I) atoms, two N-(pyridin-3-ylmeth­yl)pyridine-2-amine ligands (A and B) and two CF(3)SO(3) (−) anions. One Ag(I) atom is coordinated by two pyridine N atoms from two symmetry-related A ligands in a geometry slightly distorted from linear [N—Ag—N = 173.2 (3)°], forming a left-handed helical chain, while the other Ag(I) atom is coordinated by two pyridine N atoms from two symmetry-related B ligands in a bent arrangement [N—Ag—N = 157.1 (3)°], forming a right-handed helical chain. Both helical chains have the same pitch length [10.4007 (7) Å], propagate along the b-axis direction and are alternately arranged via Ag⋯Ag [3.0897 (12) Å] and π–π stacking inter­actions [centroid–centroid distances = 3.564 (7) and 3.518 (6) Å], resulting in the formation of a two-dimensional supra­molecular network extending parallel to the ab plane. Inter­molecular N—H⋯O, C—H⋯O and C—H⋯F hydrogen-bonding inter­actions occur between the helical chains and the anions. International Union of Crystallography 2013-06-26 /pmc/articles/PMC3772439/ /pubmed/24046582 http://dx.doi.org/10.1107/S1600536813016309 Text en © Moon and Park 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Moon, Suk-Hee
Park, Ki-Min
catena-Poly[[silver(I)-μ-N-(pyridin-3-ylmeth­yl)pyridine-2-amine-κ(2) N:N′] tri­fluoro­methane­sulfonate]
title catena-Poly[[silver(I)-μ-N-(pyridin-3-ylmeth­yl)pyridine-2-amine-κ(2) N:N′] tri­fluoro­methane­sulfonate]
title_full catena-Poly[[silver(I)-μ-N-(pyridin-3-ylmeth­yl)pyridine-2-amine-κ(2) N:N′] tri­fluoro­methane­sulfonate]
title_fullStr catena-Poly[[silver(I)-μ-N-(pyridin-3-ylmeth­yl)pyridine-2-amine-κ(2) N:N′] tri­fluoro­methane­sulfonate]
title_full_unstemmed catena-Poly[[silver(I)-μ-N-(pyridin-3-ylmeth­yl)pyridine-2-amine-κ(2) N:N′] tri­fluoro­methane­sulfonate]
title_short catena-Poly[[silver(I)-μ-N-(pyridin-3-ylmeth­yl)pyridine-2-amine-κ(2) N:N′] tri­fluoro­methane­sulfonate]
title_sort catena-poly[[silver(i)-μ-n-(pyridin-3-ylmeth­yl)pyridine-2-amine-κ(2) n:n′] tri­fluoro­methane­sulfonate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772439/
https://www.ncbi.nlm.nih.gov/pubmed/24046582
http://dx.doi.org/10.1107/S1600536813016309
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