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catena-Poly[(diaquacadmium)-μ-iminodiacetato-κ(4) O,N,O′:O′′]
In the title compound, [Cd(C(4)H(5)NO(4))(H(2)O)(2)](n), the Cd(II) atom exhibits a distorted octahedral coordination geometry, defined by one N atom and three O atoms from two iminodiacetate (IDA) ligands and two water molecules. The tridentate IDA ligand additionally bridges via one of its carbo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772440/ https://www.ncbi.nlm.nih.gov/pubmed/24046583 http://dx.doi.org/10.1107/S1600536813017121 |
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author | Pan, Gang-Hong Tang, Jin-Niu Huang, Zhong-Jing Liao, Yi-Fan Mo, Bo-Fa |
author_facet | Pan, Gang-Hong Tang, Jin-Niu Huang, Zhong-Jing Liao, Yi-Fan Mo, Bo-Fa |
author_sort | Pan, Gang-Hong |
collection | PubMed |
description | In the title compound, [Cd(C(4)H(5)NO(4))(H(2)O)(2)](n), the Cd(II) atom exhibits a distorted octahedral coordination geometry, defined by one N atom and three O atoms from two iminodiacetate (IDA) ligands and two water molecules. The tridentate IDA ligand additionally bridges via one of its carboxylate O atoms to another Cd(II) atom, thus forming a zigzag chain along [001]. A three-dimensional network is completed by intermolecular O—H⋯O and N—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3772440 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37724402013-09-17 catena-Poly[(diaquacadmium)-μ-iminodiacetato-κ(4) O,N,O′:O′′] Pan, Gang-Hong Tang, Jin-Niu Huang, Zhong-Jing Liao, Yi-Fan Mo, Bo-Fa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(4)H(5)NO(4))(H(2)O)(2)](n), the Cd(II) atom exhibits a distorted octahedral coordination geometry, defined by one N atom and three O atoms from two iminodiacetate (IDA) ligands and two water molecules. The tridentate IDA ligand additionally bridges via one of its carboxylate O atoms to another Cd(II) atom, thus forming a zigzag chain along [001]. A three-dimensional network is completed by intermolecular O—H⋯O and N—H⋯O hydrogen bonds. International Union of Crystallography 2013-06-26 /pmc/articles/PMC3772440/ /pubmed/24046583 http://dx.doi.org/10.1107/S1600536813017121 Text en © Pan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Pan, Gang-Hong Tang, Jin-Niu Huang, Zhong-Jing Liao, Yi-Fan Mo, Bo-Fa catena-Poly[(diaquacadmium)-μ-iminodiacetato-κ(4) O,N,O′:O′′] |
title |
catena-Poly[(diaquacadmium)-μ-iminodiacetato-κ(4)
O,N,O′:O′′] |
title_full |
catena-Poly[(diaquacadmium)-μ-iminodiacetato-κ(4)
O,N,O′:O′′] |
title_fullStr |
catena-Poly[(diaquacadmium)-μ-iminodiacetato-κ(4)
O,N,O′:O′′] |
title_full_unstemmed |
catena-Poly[(diaquacadmium)-μ-iminodiacetato-κ(4)
O,N,O′:O′′] |
title_short |
catena-Poly[(diaquacadmium)-μ-iminodiacetato-κ(4)
O,N,O′:O′′] |
title_sort | catena-poly[(diaquacadmium)-μ-iminodiacetato-κ(4)
o,n,o′:o′′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772440/ https://www.ncbi.nlm.nih.gov/pubmed/24046583 http://dx.doi.org/10.1107/S1600536813017121 |
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