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{2,2′-[(1,2-Dicyanoethene-1,2-diyl)bis(nitrilomethanylylidyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)zinc
In the title complex, [Zn(C(18)H(10)N(4)O(2))(CH(4)O)], the Zn(2+) cation is located on a mirror plane and is coordinated by a tetradentate Schiff base ligand anion (L (2−)) and a methanol molecule. The Zn(2+) cation is surrounded by two N atoms and two O atoms from L (2−), in a nearly planar confi...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772442/ https://www.ncbi.nlm.nih.gov/pubmed/24046585 http://dx.doi.org/10.1107/S1600536813016863 |
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author | Wang, Zhi-Chun Chu, Jing Zhan, Shu-Zhong |
author_facet | Wang, Zhi-Chun Chu, Jing Zhan, Shu-Zhong |
author_sort | Wang, Zhi-Chun |
collection | PubMed |
description | In the title complex, [Zn(C(18)H(10)N(4)O(2))(CH(4)O)], the Zn(2+) cation is located on a mirror plane and is coordinated by a tetradentate Schiff base ligand anion (L (2−)) and a methanol molecule. The Zn(2+) cation is surrounded by two N atoms and two O atoms from L (2−), in a nearly planar configuration, and one methanol O atom, forming a slightly distorted square-pyramidal geometry. The methanol molecule is disordered over two sets of sites in a 0.5:0.5 ratio. In the crystal, O—H⋯O hydrogen bonds link the molecules into chains parallel to [001]. |
format | Online Article Text |
id | pubmed-3772442 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37724422013-09-17 {2,2′-[(1,2-Dicyanoethene-1,2-diyl)bis(nitrilomethanylylidyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)zinc Wang, Zhi-Chun Chu, Jing Zhan, Shu-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(18)H(10)N(4)O(2))(CH(4)O)], the Zn(2+) cation is located on a mirror plane and is coordinated by a tetradentate Schiff base ligand anion (L (2−)) and a methanol molecule. The Zn(2+) cation is surrounded by two N atoms and two O atoms from L (2−), in a nearly planar configuration, and one methanol O atom, forming a slightly distorted square-pyramidal geometry. The methanol molecule is disordered over two sets of sites in a 0.5:0.5 ratio. In the crystal, O—H⋯O hydrogen bonds link the molecules into chains parallel to [001]. International Union of Crystallography 2013-06-29 /pmc/articles/PMC3772442/ /pubmed/24046585 http://dx.doi.org/10.1107/S1600536813016863 Text en © Wang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Zhi-Chun Chu, Jing Zhan, Shu-Zhong {2,2′-[(1,2-Dicyanoethene-1,2-diyl)bis(nitrilomethanylylidyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)zinc |
title | {2,2′-[(1,2-Dicyanoethene-1,2-diyl)bis(nitrilomethanylylidyne)]diphenolato-κ(4)
O,N,N′,O′}(methanol-κO)zinc |
title_full | {2,2′-[(1,2-Dicyanoethene-1,2-diyl)bis(nitrilomethanylylidyne)]diphenolato-κ(4)
O,N,N′,O′}(methanol-κO)zinc |
title_fullStr | {2,2′-[(1,2-Dicyanoethene-1,2-diyl)bis(nitrilomethanylylidyne)]diphenolato-κ(4)
O,N,N′,O′}(methanol-κO)zinc |
title_full_unstemmed | {2,2′-[(1,2-Dicyanoethene-1,2-diyl)bis(nitrilomethanylylidyne)]diphenolato-κ(4)
O,N,N′,O′}(methanol-κO)zinc |
title_short | {2,2′-[(1,2-Dicyanoethene-1,2-diyl)bis(nitrilomethanylylidyne)]diphenolato-κ(4)
O,N,N′,O′}(methanol-κO)zinc |
title_sort | {2,2′-[(1,2-dicyanoethene-1,2-diyl)bis(nitrilomethanylylidyne)]diphenolato-κ(4)
o,n,n′,o′}(methanol-κo)zinc |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772442/ https://www.ncbi.nlm.nih.gov/pubmed/24046585 http://dx.doi.org/10.1107/S1600536813016863 |
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