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{2,2′-[(1,2-Di­cyano­ethene-1,2-di­yl)bis­(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)zinc

In the title complex, [Zn(C(18)H(10)N(4)O(2))(CH(4)O)], the Zn(2+) cation is located on a mirror plane and is coordinated by a tetradentate Schiff base ligand anion (L (2−)) and a methanol mol­ecule. The Zn(2+) cation is surrounded by two N atoms and two O atoms from L (2−), in a nearly planar confi...

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Detalles Bibliográficos
Autores principales: Wang, Zhi-Chun, Chu, Jing, Zhan, Shu-Zhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772442/
https://www.ncbi.nlm.nih.gov/pubmed/24046585
http://dx.doi.org/10.1107/S1600536813016863
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author Wang, Zhi-Chun
Chu, Jing
Zhan, Shu-Zhong
author_facet Wang, Zhi-Chun
Chu, Jing
Zhan, Shu-Zhong
author_sort Wang, Zhi-Chun
collection PubMed
description In the title complex, [Zn(C(18)H(10)N(4)O(2))(CH(4)O)], the Zn(2+) cation is located on a mirror plane and is coordinated by a tetradentate Schiff base ligand anion (L (2−)) and a methanol mol­ecule. The Zn(2+) cation is surrounded by two N atoms and two O atoms from L (2−), in a nearly planar configuration, and one methanol O atom, forming a slightly distorted square-pyramidal geometry. The methanol molecule is disordered over two sets of sites in a 0.5:0.5 ratio. In the crystal, O—H⋯O hydrogen bonds link the mol­ecules into chains parallel to [001].
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spelling pubmed-37724422013-09-17 {2,2′-[(1,2-Di­cyano­ethene-1,2-di­yl)bis­(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)zinc Wang, Zhi-Chun Chu, Jing Zhan, Shu-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(18)H(10)N(4)O(2))(CH(4)O)], the Zn(2+) cation is located on a mirror plane and is coordinated by a tetradentate Schiff base ligand anion (L (2−)) and a methanol mol­ecule. The Zn(2+) cation is surrounded by two N atoms and two O atoms from L (2−), in a nearly planar configuration, and one methanol O atom, forming a slightly distorted square-pyramidal geometry. The methanol molecule is disordered over two sets of sites in a 0.5:0.5 ratio. In the crystal, O—H⋯O hydrogen bonds link the mol­ecules into chains parallel to [001]. International Union of Crystallography 2013-06-29 /pmc/articles/PMC3772442/ /pubmed/24046585 http://dx.doi.org/10.1107/S1600536813016863 Text en © Wang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Zhi-Chun
Chu, Jing
Zhan, Shu-Zhong
{2,2′-[(1,2-Di­cyano­ethene-1,2-di­yl)bis­(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)zinc
title {2,2′-[(1,2-Di­cyano­ethene-1,2-di­yl)bis­(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)zinc
title_full {2,2′-[(1,2-Di­cyano­ethene-1,2-di­yl)bis­(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)zinc
title_fullStr {2,2′-[(1,2-Di­cyano­ethene-1,2-di­yl)bis­(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)zinc
title_full_unstemmed {2,2′-[(1,2-Di­cyano­ethene-1,2-di­yl)bis­(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)zinc
title_short {2,2′-[(1,2-Di­cyano­ethene-1,2-di­yl)bis­(nitrilo­methanylyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)zinc
title_sort {2,2′-[(1,2-di­cyano­ethene-1,2-di­yl)bis­(nitrilo­methanylyl­idyne)]diphenolato-κ(4) o,n,n′,o′}(methanol-κo)zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772442/
https://www.ncbi.nlm.nih.gov/pubmed/24046585
http://dx.doi.org/10.1107/S1600536813016863
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