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trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)cobalt(II) dihydrate

The title compound, [Co(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, contains a Co(II) ion on an inversion center, exhibiting an octa­hedral coordination geometry. The equatorial plane is formed by two trans-related N,O-bidentate pyridazine-3-carboxyl­ate ligands and the axial positions are occupied by t...

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Detalles Bibliográficos
Autores principales: Artetxe, Beñat, Reinoso, Santiago, San Felices, Leire, Martín-Caballero, Jagoba, Gutiérrez-Zorrilla, Juan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772443/
https://www.ncbi.nlm.nih.gov/pubmed/24046586
http://dx.doi.org/10.1107/S1600536813017340
Descripción
Sumario:The title compound, [Co(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, contains a Co(II) ion on an inversion center, exhibiting an octa­hedral coordination geometry. The equatorial plane is formed by two trans-related N,O-bidentate pyridazine-3-carboxyl­ate ligands and the axial positions are occupied by two water mol­ecules. The Co(II) complex mol­ecules are stacked in a column along the a-axis direction by an O—H⋯N hydrogen bond between the non-coordinating pyridazine N atom and the coordinating water mol­ecule. These columns are further connected into a layer parallel to the ac plane by additional hydrogen bonds involving the coordinating and non-coordinating water mol­ecules, and the non-coordinating carboxyl­ate O atom. The crystal packing is completed by inter­layer weak C—H⋯O inter­actions.