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trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)cobalt(II) dihydrate

The title compound, [Co(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, contains a Co(II) ion on an inversion center, exhibiting an octa­hedral coordination geometry. The equatorial plane is formed by two trans-related N,O-bidentate pyridazine-3-carboxyl­ate ligands and the axial positions are occupied by t...

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Autores principales: Artetxe, Beñat, Reinoso, Santiago, San Felices, Leire, Martín-Caballero, Jagoba, Gutiérrez-Zorrilla, Juan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772443/
https://www.ncbi.nlm.nih.gov/pubmed/24046586
http://dx.doi.org/10.1107/S1600536813017340
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author Artetxe, Beñat
Reinoso, Santiago
San Felices, Leire
Martín-Caballero, Jagoba
Gutiérrez-Zorrilla, Juan M.
author_facet Artetxe, Beñat
Reinoso, Santiago
San Felices, Leire
Martín-Caballero, Jagoba
Gutiérrez-Zorrilla, Juan M.
author_sort Artetxe, Beñat
collection PubMed
description The title compound, [Co(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, contains a Co(II) ion on an inversion center, exhibiting an octa­hedral coordination geometry. The equatorial plane is formed by two trans-related N,O-bidentate pyridazine-3-carboxyl­ate ligands and the axial positions are occupied by two water mol­ecules. The Co(II) complex mol­ecules are stacked in a column along the a-axis direction by an O—H⋯N hydrogen bond between the non-coordinating pyridazine N atom and the coordinating water mol­ecule. These columns are further connected into a layer parallel to the ac plane by additional hydrogen bonds involving the coordinating and non-coordinating water mol­ecules, and the non-coordinating carboxyl­ate O atom. The crystal packing is completed by inter­layer weak C—H⋯O inter­actions.
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spelling pubmed-37724432013-09-17 trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)cobalt(II) dihydrate Artetxe, Beñat Reinoso, Santiago San Felices, Leire Martín-Caballero, Jagoba Gutiérrez-Zorrilla, Juan M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, contains a Co(II) ion on an inversion center, exhibiting an octa­hedral coordination geometry. The equatorial plane is formed by two trans-related N,O-bidentate pyridazine-3-carboxyl­ate ligands and the axial positions are occupied by two water mol­ecules. The Co(II) complex mol­ecules are stacked in a column along the a-axis direction by an O—H⋯N hydrogen bond between the non-coordinating pyridazine N atom and the coordinating water mol­ecule. These columns are further connected into a layer parallel to the ac plane by additional hydrogen bonds involving the coordinating and non-coordinating water mol­ecules, and the non-coordinating carboxyl­ate O atom. The crystal packing is completed by inter­layer weak C—H⋯O inter­actions. International Union of Crystallography 2013-06-29 /pmc/articles/PMC3772443/ /pubmed/24046586 http://dx.doi.org/10.1107/S1600536813017340 Text en © Artetxe et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Artetxe, Beñat
Reinoso, Santiago
San Felices, Leire
Martín-Caballero, Jagoba
Gutiérrez-Zorrilla, Juan M.
trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)cobalt(II) dihydrate
title trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)cobalt(II) dihydrate
title_full trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)cobalt(II) dihydrate
title_fullStr trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)cobalt(II) dihydrate
title_full_unstemmed trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)cobalt(II) dihydrate
title_short trans-Di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) N (2),O)cobalt(II) dihydrate
title_sort trans-di­aqua­bis­(pyridazine-3-carboxyl­ato-κ(2) n (2),o)cobalt(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772443/
https://www.ncbi.nlm.nih.gov/pubmed/24046586
http://dx.doi.org/10.1107/S1600536813017340
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