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Poly[μ(2)-aqua-μ(4)-[1-(4-chlorophenyl)-4,4,4-trifluorobutane-1,3-dionato]-potassium]
In the title compound, [K(C(10)H(5)ClO(2)F(3))(H(2)O)](n), the two independent K(+) ions are located on a twofold rotation axis. For each of the cations, the distorted cubic coordination environment is defined by two F and four O atoms of symmetry-related 1,4-chlorophenyl-4,4,4-trifluorobutane-1,...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772444/ https://www.ncbi.nlm.nih.gov/pubmed/24046587 http://dx.doi.org/10.1107/S1600536813017388 |
Sumario: | In the title compound, [K(C(10)H(5)ClO(2)F(3))(H(2)O)](n), the two independent K(+) ions are located on a twofold rotation axis. For each of the cations, the distorted cubic coordination environment is defined by two F and four O atoms of symmetry-related 1,4-chlorophenyl-4,4,4-trifluorobutane-1,3-dionate anions and by two O atoms of water molecules. The μ(4)-bridging character of the anion and the μ(2)-bridging of the water molecule lead to the formation of layers parallel to (100). The coordinating water molecules are also involved in O—H⋯O hydrogen bonds that reinforce the molecular cohesion within the layers, which are stacked along [100]. The β-diketonate anion is not planar, with an angle of 31.78 (10)° between the mean planes of the diketonate group and the chlorophenyl ring. |
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