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Poly[μ(2)-aqua-μ(4)-[1-(4-chloro­phen­yl)-4,4,4-tri­fluoro­butane-1,3-dionato]-potassium]

In the title compound, [K(C(10)H(5)ClO(2)F(3))(H(2)O)](n), the two independent K(+) ions are located on a twofold rotation axis. For each of the cations, the distorted cubic coordination environment is defined by two F and four O atoms of symmetry-related 1,4-chloro­phenyl-4,4,4-tri­fluoro­butane-1,...

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Detalles Bibliográficos
Autores principales: Martins, João P., Arranja, Cláudia C., Sobral, Abílio J. F. N., Ramos Silva, Manuela
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772444/
https://www.ncbi.nlm.nih.gov/pubmed/24046587
http://dx.doi.org/10.1107/S1600536813017388
Descripción
Sumario:In the title compound, [K(C(10)H(5)ClO(2)F(3))(H(2)O)](n), the two independent K(+) ions are located on a twofold rotation axis. For each of the cations, the distorted cubic coordination environment is defined by two F and four O atoms of symmetry-related 1,4-chloro­phenyl-4,4,4-tri­fluoro­butane-1,3-dionate anions and by two O atoms of water mol­ecules. The μ(4)-bridging character of the anion and the μ(2)-bridging of the water mol­ecule lead to the formation of layers parallel to (100). The coordinating water mol­ecules are also involved in O—H⋯O hydrogen bonds that reinforce the mol­ecular cohesion within the layers, which are stacked along [100]. The β-diketonate anion is not planar, with an angle of 31.78 (10)° between the mean planes of the diketonate group and the chloro­phenyl ring.