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Poly[μ(2)-aqua-μ(4)-[1-(4-chlorophenyl)-4,4,4-trifluorobutane-1,3-dionato]-potassium]
In the title compound, [K(C(10)H(5)ClO(2)F(3))(H(2)O)](n), the two independent K(+) ions are located on a twofold rotation axis. For each of the cations, the distorted cubic coordination environment is defined by two F and four O atoms of symmetry-related 1,4-chlorophenyl-4,4,4-trifluorobutane-1,...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772444/ https://www.ncbi.nlm.nih.gov/pubmed/24046587 http://dx.doi.org/10.1107/S1600536813017388 |
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author | Martins, João P. Arranja, Cláudia C. Sobral, Abílio J. F. N. Ramos Silva, Manuela |
author_facet | Martins, João P. Arranja, Cláudia C. Sobral, Abílio J. F. N. Ramos Silva, Manuela |
author_sort | Martins, João P. |
collection | PubMed |
description | In the title compound, [K(C(10)H(5)ClO(2)F(3))(H(2)O)](n), the two independent K(+) ions are located on a twofold rotation axis. For each of the cations, the distorted cubic coordination environment is defined by two F and four O atoms of symmetry-related 1,4-chlorophenyl-4,4,4-trifluorobutane-1,3-dionate anions and by two O atoms of water molecules. The μ(4)-bridging character of the anion and the μ(2)-bridging of the water molecule lead to the formation of layers parallel to (100). The coordinating water molecules are also involved in O—H⋯O hydrogen bonds that reinforce the molecular cohesion within the layers, which are stacked along [100]. The β-diketonate anion is not planar, with an angle of 31.78 (10)° between the mean planes of the diketonate group and the chlorophenyl ring. |
format | Online Article Text |
id | pubmed-3772444 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37724442013-09-17 Poly[μ(2)-aqua-μ(4)-[1-(4-chlorophenyl)-4,4,4-trifluorobutane-1,3-dionato]-potassium] Martins, João P. Arranja, Cláudia C. Sobral, Abílio J. F. N. Ramos Silva, Manuela Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [K(C(10)H(5)ClO(2)F(3))(H(2)O)](n), the two independent K(+) ions are located on a twofold rotation axis. For each of the cations, the distorted cubic coordination environment is defined by two F and four O atoms of symmetry-related 1,4-chlorophenyl-4,4,4-trifluorobutane-1,3-dionate anions and by two O atoms of water molecules. The μ(4)-bridging character of the anion and the μ(2)-bridging of the water molecule lead to the formation of layers parallel to (100). The coordinating water molecules are also involved in O—H⋯O hydrogen bonds that reinforce the molecular cohesion within the layers, which are stacked along [100]. The β-diketonate anion is not planar, with an angle of 31.78 (10)° between the mean planes of the diketonate group and the chlorophenyl ring. International Union of Crystallography 2013-06-29 /pmc/articles/PMC3772444/ /pubmed/24046587 http://dx.doi.org/10.1107/S1600536813017388 Text en © Martins et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Martins, João P. Arranja, Cláudia C. Sobral, Abílio J. F. N. Ramos Silva, Manuela Poly[μ(2)-aqua-μ(4)-[1-(4-chlorophenyl)-4,4,4-trifluorobutane-1,3-dionato]-potassium] |
title | Poly[μ(2)-aqua-μ(4)-[1-(4-chlorophenyl)-4,4,4-trifluorobutane-1,3-dionato]-potassium] |
title_full | Poly[μ(2)-aqua-μ(4)-[1-(4-chlorophenyl)-4,4,4-trifluorobutane-1,3-dionato]-potassium] |
title_fullStr | Poly[μ(2)-aqua-μ(4)-[1-(4-chlorophenyl)-4,4,4-trifluorobutane-1,3-dionato]-potassium] |
title_full_unstemmed | Poly[μ(2)-aqua-μ(4)-[1-(4-chlorophenyl)-4,4,4-trifluorobutane-1,3-dionato]-potassium] |
title_short | Poly[μ(2)-aqua-μ(4)-[1-(4-chlorophenyl)-4,4,4-trifluorobutane-1,3-dionato]-potassium] |
title_sort | poly[μ(2)-aqua-μ(4)-[1-(4-chlorophenyl)-4,4,4-trifluorobutane-1,3-dionato]-potassium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772444/ https://www.ncbi.nlm.nih.gov/pubmed/24046587 http://dx.doi.org/10.1107/S1600536813017388 |
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