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Poly[μ(2)-aqua-μ(4)-[1-(4-chloro­phen­yl)-4,4,4-tri­fluoro­butane-1,3-dionato]-potassium]

In the title compound, [K(C(10)H(5)ClO(2)F(3))(H(2)O)](n), the two independent K(+) ions are located on a twofold rotation axis. For each of the cations, the distorted cubic coordination environment is defined by two F and four O atoms of symmetry-related 1,4-chloro­phenyl-4,4,4-tri­fluoro­butane-1,...

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Autores principales: Martins, João P., Arranja, Cláudia C., Sobral, Abílio J. F. N., Ramos Silva, Manuela
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772444/
https://www.ncbi.nlm.nih.gov/pubmed/24046587
http://dx.doi.org/10.1107/S1600536813017388
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author Martins, João P.
Arranja, Cláudia C.
Sobral, Abílio J. F. N.
Ramos Silva, Manuela
author_facet Martins, João P.
Arranja, Cláudia C.
Sobral, Abílio J. F. N.
Ramos Silva, Manuela
author_sort Martins, João P.
collection PubMed
description In the title compound, [K(C(10)H(5)ClO(2)F(3))(H(2)O)](n), the two independent K(+) ions are located on a twofold rotation axis. For each of the cations, the distorted cubic coordination environment is defined by two F and four O atoms of symmetry-related 1,4-chloro­phenyl-4,4,4-tri­fluoro­butane-1,3-dionate anions and by two O atoms of water mol­ecules. The μ(4)-bridging character of the anion and the μ(2)-bridging of the water mol­ecule lead to the formation of layers parallel to (100). The coordinating water mol­ecules are also involved in O—H⋯O hydrogen bonds that reinforce the mol­ecular cohesion within the layers, which are stacked along [100]. The β-diketonate anion is not planar, with an angle of 31.78 (10)° between the mean planes of the diketonate group and the chloro­phenyl ring.
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spelling pubmed-37724442013-09-17 Poly[μ(2)-aqua-μ(4)-[1-(4-chloro­phen­yl)-4,4,4-tri­fluoro­butane-1,3-dionato]-potassium] Martins, João P. Arranja, Cláudia C. Sobral, Abílio J. F. N. Ramos Silva, Manuela Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [K(C(10)H(5)ClO(2)F(3))(H(2)O)](n), the two independent K(+) ions are located on a twofold rotation axis. For each of the cations, the distorted cubic coordination environment is defined by two F and four O atoms of symmetry-related 1,4-chloro­phenyl-4,4,4-tri­fluoro­butane-1,3-dionate anions and by two O atoms of water mol­ecules. The μ(4)-bridging character of the anion and the μ(2)-bridging of the water mol­ecule lead to the formation of layers parallel to (100). The coordinating water mol­ecules are also involved in O—H⋯O hydrogen bonds that reinforce the mol­ecular cohesion within the layers, which are stacked along [100]. The β-diketonate anion is not planar, with an angle of 31.78 (10)° between the mean planes of the diketonate group and the chloro­phenyl ring. International Union of Crystallography 2013-06-29 /pmc/articles/PMC3772444/ /pubmed/24046587 http://dx.doi.org/10.1107/S1600536813017388 Text en © Martins et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Martins, João P.
Arranja, Cláudia C.
Sobral, Abílio J. F. N.
Ramos Silva, Manuela
Poly[μ(2)-aqua-μ(4)-[1-(4-chloro­phen­yl)-4,4,4-tri­fluoro­butane-1,3-dionato]-potassium]
title Poly[μ(2)-aqua-μ(4)-[1-(4-chloro­phen­yl)-4,4,4-tri­fluoro­butane-1,3-dionato]-potassium]
title_full Poly[μ(2)-aqua-μ(4)-[1-(4-chloro­phen­yl)-4,4,4-tri­fluoro­butane-1,3-dionato]-potassium]
title_fullStr Poly[μ(2)-aqua-μ(4)-[1-(4-chloro­phen­yl)-4,4,4-tri­fluoro­butane-1,3-dionato]-potassium]
title_full_unstemmed Poly[μ(2)-aqua-μ(4)-[1-(4-chloro­phen­yl)-4,4,4-tri­fluoro­butane-1,3-dionato]-potassium]
title_short Poly[μ(2)-aqua-μ(4)-[1-(4-chloro­phen­yl)-4,4,4-tri­fluoro­butane-1,3-dionato]-potassium]
title_sort poly[μ(2)-aqua-μ(4)-[1-(4-chloro­phen­yl)-4,4,4-tri­fluoro­butane-1,3-dionato]-potassium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772444/
https://www.ncbi.nlm.nih.gov/pubmed/24046587
http://dx.doi.org/10.1107/S1600536813017388
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