Di-μ-bromido-bis­[(diethyl ether-κO)(2,4,6-tri­methyl­phen­yl)magnesium]: the mesityl Grignard reagent

The crystal structure of the title compound, [Mg(2)Br(2)(C(9)H(11))(2)(C(4)H(10)O)(2)], features a centrosymmetric two-centre magnesium complex with half a mol­ecule in the asymmetric unit. The Mg atom is in a considerably distorted Br(2)CO coordination. Bond lengths and angles are comparable with a...

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Detalles Bibliográficos
Autores principales: Seven, Ömer, Bolte, Michael, Lerner, Hans-Wolfram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772445/
https://www.ncbi.nlm.nih.gov/pubmed/24046588
http://dx.doi.org/10.1107/S1600536813017108
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author Seven, Ömer
Bolte, Michael
Lerner, Hans-Wolfram
author_facet Seven, Ömer
Bolte, Michael
Lerner, Hans-Wolfram
author_sort Seven, Ömer
collection PubMed
description The crystal structure of the title compound, [Mg(2)Br(2)(C(9)H(11))(2)(C(4)H(10)O)(2)], features a centrosymmetric two-centre magnesium complex with half a mol­ecule in the asymmetric unit. The Mg atom is in a considerably distorted Br(2)CO coordination. Bond lengths and angles are comparable with already published values. The crystal packing is stabilized by C—H⋯π inter­actions linking the complexes into sheets parallel to (0-11).
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spelling pubmed-37724452013-09-17 Di-μ-bromido-bis­[(diethyl ether-κO)(2,4,6-tri­methyl­phen­yl)magnesium]: the mesityl Grignard reagent Seven, Ömer Bolte, Michael Lerner, Hans-Wolfram Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Mg(2)Br(2)(C(9)H(11))(2)(C(4)H(10)O)(2)], features a centrosymmetric two-centre magnesium complex with half a mol­ecule in the asymmetric unit. The Mg atom is in a considerably distorted Br(2)CO coordination. Bond lengths and angles are comparable with already published values. The crystal packing is stabilized by C—H⋯π inter­actions linking the complexes into sheets parallel to (0-11). International Union of Crystallography 2013-06-29 /pmc/articles/PMC3772445/ /pubmed/24046588 http://dx.doi.org/10.1107/S1600536813017108 Text en © Seven et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Seven, Ömer
Bolte, Michael
Lerner, Hans-Wolfram
Di-μ-bromido-bis­[(diethyl ether-κO)(2,4,6-tri­methyl­phen­yl)magnesium]: the mesityl Grignard reagent
title Di-μ-bromido-bis­[(diethyl ether-κO)(2,4,6-tri­methyl­phen­yl)magnesium]: the mesityl Grignard reagent
title_full Di-μ-bromido-bis­[(diethyl ether-κO)(2,4,6-tri­methyl­phen­yl)magnesium]: the mesityl Grignard reagent
title_fullStr Di-μ-bromido-bis­[(diethyl ether-κO)(2,4,6-tri­methyl­phen­yl)magnesium]: the mesityl Grignard reagent
title_full_unstemmed Di-μ-bromido-bis­[(diethyl ether-κO)(2,4,6-tri­methyl­phen­yl)magnesium]: the mesityl Grignard reagent
title_short Di-μ-bromido-bis­[(diethyl ether-κO)(2,4,6-tri­methyl­phen­yl)magnesium]: the mesityl Grignard reagent
title_sort di-μ-bromido-bis­[(diethyl ether-κo)(2,4,6-tri­methyl­phen­yl)magnesium]: the mesityl grignard reagent
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772445/
https://www.ncbi.nlm.nih.gov/pubmed/24046588
http://dx.doi.org/10.1107/S1600536813017108
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