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Bis(μ-6-meth­oxy-2-{[(3-oxidoprop­yl)imino]­meth­yl}phenolato)nickel(II) methanol monosolvate

The mol­ecular structure of the title complex, [Ni(2)(C(11)H(13)NO(3))(2)]·CH(3)OH, contains two Ni(II) atoms and two doubly deprotonated 6-meth­oxy-2-{[(3-oxidoprop­yl)imino]­meth­yl}phenolate ligands. The Ni(II) atoms are each four-coordinated in a distorted square-planar geometry by three O atoms...

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Detalles Bibliográficos
Autores principales: Meng, Fan-Kun, Zhang, Xin, Yi, Hua, Zhang, De-Hui, Jia, Jun-Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772446/
https://www.ncbi.nlm.nih.gov/pubmed/24046589
http://dx.doi.org/10.1107/S1600536813017224
Descripción
Sumario:The mol­ecular structure of the title complex, [Ni(2)(C(11)H(13)NO(3))(2)]·CH(3)OH, contains two Ni(II) atoms and two doubly deprotonated 6-meth­oxy-2-{[(3-oxidoprop­yl)imino]­meth­yl}phenolate ligands. The Ni(II) atoms are each four-coordinated in a distorted square-planar geometry by three O atoms and one N atom derived from the phenolate ligands. The solvent mol­ecule is linked to the complex mol­ecule by two O—H⋯O hydrogen bonds.