1,3-Alternate conformer 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetra­kis­(4-methyl­sulfanylbenz­yloxy)-2,8,14,20-tetra­thia­calix[4]arene

The title thia­calix[4]arene derivative, C(72)H(80)O(4)S(8), adopts a 1,3-alternate conformation, where the four 4-methyl­sul­fan­yl­benzyl groups are located alternately at the two sides of a virtual plane defined by the four bridging S atoms. In the crystal, there are no significant inter­molecula...

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Detalles Bibliográficos
Autores principales: Gao, Qingsong, Xie, Dexun, An, Delie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772452/
https://www.ncbi.nlm.nih.gov/pubmed/24046595
http://dx.doi.org/10.1107/S1600536813014827
Descripción
Sumario:The title thia­calix[4]arene derivative, C(72)H(80)O(4)S(8), adopts a 1,3-alternate conformation, where the four 4-methyl­sul­fan­yl­benzyl groups are located alternately at the two sides of a virtual plane defined by the four bridging S atoms. In the crystal, there are no significant inter­molecular inter­actions present. Some of the peripheral tert-butyl and methyl­sulfanyl groups are disordered over two positions. A region of disordered electron density, occupying voids of ca 700 Å(3) for an electron count of 124, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155].

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