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rac-3-(4-Hydroxybenzyl)chroman-4-one
In the racemic title compound, C(16)H(14)O(3), the ring of the 4-hydroxybenzyl substituent group forms a dihedral angle of 80.12 (12)° with the benzene ring of the chromanone system. Two C atoms of the pyranone ring and the H atoms on the benzyl α-C atom are disordered over two sites, with site-o...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772453/ https://www.ncbi.nlm.nih.gov/pubmed/24046596 http://dx.doi.org/10.1107/S1600536813014645 |
Sumario: | In the racemic title compound, C(16)H(14)O(3), the ring of the 4-hydroxybenzyl substituent group forms a dihedral angle of 80.12 (12)° with the benzene ring of the chromanone system. Two C atoms of the pyranone ring and the H atoms on the benzyl α-C atom are disordered over two sites, with site-occupation factors of 0.818 (8) and 0.182 (8). The crystal structure is stabilized by O—H⋯O hydrogen bonds, which form parallel one-dimensional zigzag chains down the c axis and are interconnected by both methine C—H⋯O hydrogen bonds and weak aromatic C—H⋯π interactions, giving a sheet structure lying parallel to [011]. |
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