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1-[(6-Chloro­pyridin-3-yl)meth­yl]-10-nitro-1,2,3,5,6,7,8,9-octa­hydro-5,9-methano­imidazo[1,2-a]azocin-5-ol

In the title compound, C(16)H(19)ClN(4)O(3), the cyclo­hexane ring displays a chair formation and the tetra­hydro­pyridine ring displays an envelope conformation with the methyl­ene C atom as the flap; the imidazolidine ring also displays an envelope conformation with a methyl­ene C atom as the flap...

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Detalles Bibliográficos
Autores principales: Cui, Shu-Xia, Zhang, Guang-You, Tian, Zhong-Zhen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772455/
https://www.ncbi.nlm.nih.gov/pubmed/24046598
http://dx.doi.org/10.1107/S1600536813014402
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author Cui, Shu-Xia
Zhang, Guang-You
Tian, Zhong-Zhen
author_facet Cui, Shu-Xia
Zhang, Guang-You
Tian, Zhong-Zhen
author_sort Cui, Shu-Xia
collection PubMed
description In the title compound, C(16)H(19)ClN(4)O(3), the cyclo­hexane ring displays a chair formation and the tetra­hydro­pyridine ring displays an envelope conformation with the methyl­ene C atom as the flap; the imidazolidine ring also displays an envelope conformation with a methyl­ene C atom as the flap. In the crystal, O—H⋯N hydrogen bonds between hy­droxy groups and pyridine rings link inversion-related mol­ecules into dimers. Weak C—H⋯O hydrogen bonds further link the dimers into supra­molecular chains running along the c axis.
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spelling pubmed-37724552013-09-17 1-[(6-Chloro­pyridin-3-yl)meth­yl]-10-nitro-1,2,3,5,6,7,8,9-octa­hydro-5,9-methano­imidazo[1,2-a]azocin-5-ol Cui, Shu-Xia Zhang, Guang-You Tian, Zhong-Zhen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(19)ClN(4)O(3), the cyclo­hexane ring displays a chair formation and the tetra­hydro­pyridine ring displays an envelope conformation with the methyl­ene C atom as the flap; the imidazolidine ring also displays an envelope conformation with a methyl­ene C atom as the flap. In the crystal, O—H⋯N hydrogen bonds between hy­droxy groups and pyridine rings link inversion-related mol­ecules into dimers. Weak C—H⋯O hydrogen bonds further link the dimers into supra­molecular chains running along the c axis. International Union of Crystallography 2013-06-08 /pmc/articles/PMC3772455/ /pubmed/24046598 http://dx.doi.org/10.1107/S1600536813014402 Text en © Cui et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cui, Shu-Xia
Zhang, Guang-You
Tian, Zhong-Zhen
1-[(6-Chloro­pyridin-3-yl)meth­yl]-10-nitro-1,2,3,5,6,7,8,9-octa­hydro-5,9-methano­imidazo[1,2-a]azocin-5-ol
title 1-[(6-Chloro­pyridin-3-yl)meth­yl]-10-nitro-1,2,3,5,6,7,8,9-octa­hydro-5,9-methano­imidazo[1,2-a]azocin-5-ol
title_full 1-[(6-Chloro­pyridin-3-yl)meth­yl]-10-nitro-1,2,3,5,6,7,8,9-octa­hydro-5,9-methano­imidazo[1,2-a]azocin-5-ol
title_fullStr 1-[(6-Chloro­pyridin-3-yl)meth­yl]-10-nitro-1,2,3,5,6,7,8,9-octa­hydro-5,9-methano­imidazo[1,2-a]azocin-5-ol
title_full_unstemmed 1-[(6-Chloro­pyridin-3-yl)meth­yl]-10-nitro-1,2,3,5,6,7,8,9-octa­hydro-5,9-methano­imidazo[1,2-a]azocin-5-ol
title_short 1-[(6-Chloro­pyridin-3-yl)meth­yl]-10-nitro-1,2,3,5,6,7,8,9-octa­hydro-5,9-methano­imidazo[1,2-a]azocin-5-ol
title_sort 1-[(6-chloro­pyridin-3-yl)meth­yl]-10-nitro-1,2,3,5,6,7,8,9-octa­hydro-5,9-methano­imidazo[1,2-a]azocin-5-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772455/
https://www.ncbi.nlm.nih.gov/pubmed/24046598
http://dx.doi.org/10.1107/S1600536813014402
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