N-[(3-Ethyl­phen­yl)carbamo­thio­yl]-2,2-di­phenyl­acetamide

In the title mol­ecule, C(23)H(22)N(2)OS, the di­phenyl­acetyl and ethyl­benzene groups adopt a trans–cis conformation, respectively, with respect to the S atom across the (S=)C—N bonds. This conformation is stabilized by an intra­molecular N—H⋯O hydrogen bond and a weak C—H⋯S hydrogen bond. The eth...

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Autores principales: Yusof, Mohd Sukeri Mohd, Razali, Nur Rafikah, Arshad, Suhana, Rahman, Azhar Abdul, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772456/
https://www.ncbi.nlm.nih.gov/pubmed/24046599
http://dx.doi.org/10.1107/S1600536813014268
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author Yusof, Mohd Sukeri Mohd
Razali, Nur Rafikah
Arshad, Suhana
Rahman, Azhar Abdul
Razak, Ibrahim Abdul
author_facet Yusof, Mohd Sukeri Mohd
Razali, Nur Rafikah
Arshad, Suhana
Rahman, Azhar Abdul
Razak, Ibrahim Abdul
author_sort Yusof, Mohd Sukeri Mohd
collection PubMed
description In the title mol­ecule, C(23)H(22)N(2)OS, the di­phenyl­acetyl and ethyl­benzene groups adopt a trans–cis conformation, respectively, with respect to the S atom across the (S=)C—N bonds. This conformation is stabilized by an intra­molecular N—H⋯O hydrogen bond and a weak C—H⋯S hydrogen bond. The ethyl-substituted benzene ring forms dihedral angles of 87.53 (15) and 73.94 (15)° with the phenyl rings. In the crystal, N—H⋯O hydrogen bonds link mol­ecules into chains along [100]. A weak C—H⋯π inter­action is also observed.
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spelling pubmed-37724562013-09-17 N-[(3-Ethyl­phen­yl)carbamo­thio­yl]-2,2-di­phenyl­acetamide Yusof, Mohd Sukeri Mohd Razali, Nur Rafikah Arshad, Suhana Rahman, Azhar Abdul Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(23)H(22)N(2)OS, the di­phenyl­acetyl and ethyl­benzene groups adopt a trans–cis conformation, respectively, with respect to the S atom across the (S=)C—N bonds. This conformation is stabilized by an intra­molecular N—H⋯O hydrogen bond and a weak C—H⋯S hydrogen bond. The ethyl-substituted benzene ring forms dihedral angles of 87.53 (15) and 73.94 (15)° with the phenyl rings. In the crystal, N—H⋯O hydrogen bonds link mol­ecules into chains along [100]. A weak C—H⋯π inter­action is also observed. International Union of Crystallography 2013-06-08 /pmc/articles/PMC3772456/ /pubmed/24046599 http://dx.doi.org/10.1107/S1600536813014268 Text en © Yusof et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yusof, Mohd Sukeri Mohd
Razali, Nur Rafikah
Arshad, Suhana
Rahman, Azhar Abdul
Razak, Ibrahim Abdul
N-[(3-Ethyl­phen­yl)carbamo­thio­yl]-2,2-di­phenyl­acetamide
title N-[(3-Ethyl­phen­yl)carbamo­thio­yl]-2,2-di­phenyl­acetamide
title_full N-[(3-Ethyl­phen­yl)carbamo­thio­yl]-2,2-di­phenyl­acetamide
title_fullStr N-[(3-Ethyl­phen­yl)carbamo­thio­yl]-2,2-di­phenyl­acetamide
title_full_unstemmed N-[(3-Ethyl­phen­yl)carbamo­thio­yl]-2,2-di­phenyl­acetamide
title_short N-[(3-Ethyl­phen­yl)carbamo­thio­yl]-2,2-di­phenyl­acetamide
title_sort n-[(3-ethyl­phen­yl)carbamo­thio­yl]-2,2-di­phenyl­acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772456/
https://www.ncbi.nlm.nih.gov/pubmed/24046599
http://dx.doi.org/10.1107/S1600536813014268
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