5,15-Bis(4-pentyl­oxyphen­yl)porphyrin

In the title compound, C(42)H(42)N(4)O(2), the complete molecule is generated by a crystallographic inversion centre. The porphyrin system exhibits a near planar macrocycle conformation with an average deviation from the least-squares plane of the 24 macrocycle atoms of 0.037 (5) Å. The phenyl ipso...

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Detalles Bibliográficos
Autor principal: Senge, Mathias O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772480/
https://www.ncbi.nlm.nih.gov/pubmed/24046623
http://dx.doi.org/10.1107/S160053681301550X
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author Senge, Mathias O.
author_facet Senge, Mathias O.
author_sort Senge, Mathias O.
collection PubMed
description In the title compound, C(42)H(42)N(4)O(2), the complete molecule is generated by a crystallographic inversion centre. The porphyrin system exhibits a near planar macrocycle conformation with an average deviation from the least-squares plane of the 24 macrocycle atoms of 0.037 (5) Å. The phenyl ipso C atoms are positioned above and below the porphyrin plane by 0.35 (1) Å and the macrocycle shows evidence of in-plane rectangular elongation with N⋯N separations of 3.032 (5) and 2.803 (5) Å. Two intramolecular N—H⋯N hydrogen bonds occur.
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spelling pubmed-37724802013-09-17 5,15-Bis(4-pentyl­oxyphen­yl)porphyrin Senge, Mathias O. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(42)H(42)N(4)O(2), the complete molecule is generated by a crystallographic inversion centre. The porphyrin system exhibits a near planar macrocycle conformation with an average deviation from the least-squares plane of the 24 macrocycle atoms of 0.037 (5) Å. The phenyl ipso C atoms are positioned above and below the porphyrin plane by 0.35 (1) Å and the macrocycle shows evidence of in-plane rectangular elongation with N⋯N separations of 3.032 (5) and 2.803 (5) Å. Two intramolecular N—H⋯N hydrogen bonds occur. International Union of Crystallography 2013-06-08 /pmc/articles/PMC3772480/ /pubmed/24046623 http://dx.doi.org/10.1107/S160053681301550X Text en © Mathias O. Senge 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Senge, Mathias O.
5,15-Bis(4-pentyl­oxyphen­yl)porphyrin
title 5,15-Bis(4-pentyl­oxyphen­yl)porphyrin
title_full 5,15-Bis(4-pentyl­oxyphen­yl)porphyrin
title_fullStr 5,15-Bis(4-pentyl­oxyphen­yl)porphyrin
title_full_unstemmed 5,15-Bis(4-pentyl­oxyphen­yl)porphyrin
title_short 5,15-Bis(4-pentyl­oxyphen­yl)porphyrin
title_sort 5,15-bis(4-pentyl­oxyphen­yl)porphyrin
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772480/
https://www.ncbi.nlm.nih.gov/pubmed/24046623
http://dx.doi.org/10.1107/S160053681301550X
work_keys_str_mv AT sengemathiaso 515bis4pentyloxyphenylporphyrin

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