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Methyl 4-anilino-2′,5-dioxo-1′,2′-di­hydro-5H-spiro­[furan-2,3′-indole]-3-carboxyl­ate

In the title compound, C(19)H(14)N(2)O(5), the spiro junction links an oxindole moeity and a furan ring, which subtend a dihedral angle of 83.49 (6)°. The mol­ecular structure features an N—H⋯O hydrogen bond, which generates an S(6) ring motif. The crystal packing is governed by two N—H⋯O inter­acti...

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Autores principales: Gangadharan, Rajeswari, Sethusankar, K., Kiruthika, Selvarangam E., Perumal, P. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772486/
https://www.ncbi.nlm.nih.gov/pubmed/24046629
http://dx.doi.org/10.1107/S1600536813014967
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author Gangadharan, Rajeswari
Sethusankar, K.
Kiruthika, Selvarangam E.
Perumal, P. T.
author_facet Gangadharan, Rajeswari
Sethusankar, K.
Kiruthika, Selvarangam E.
Perumal, P. T.
author_sort Gangadharan, Rajeswari
collection PubMed
description In the title compound, C(19)H(14)N(2)O(5), the spiro junction links an oxindole moeity and a furan ring, which subtend a dihedral angle of 83.49 (6)°. The mol­ecular structure features an N—H⋯O hydrogen bond, which generates an S(6) ring motif. The crystal packing is governed by two N—H⋯O inter­actions, one of which generates a centrosymmetric R (2) (2)(14) dimer. The other N—H⋯O inter­action along with a C—H⋯O hydrogen bond contributes to the formation of a C (2) (2)[R (2) (2)(9)] dimeric chain running along the b-axis direction.
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spelling pubmed-37724862013-09-17 Methyl 4-anilino-2′,5-dioxo-1′,2′-di­hydro-5H-spiro­[furan-2,3′-indole]-3-carboxyl­ate Gangadharan, Rajeswari Sethusankar, K. Kiruthika, Selvarangam E. Perumal, P. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(14)N(2)O(5), the spiro junction links an oxindole moeity and a furan ring, which subtend a dihedral angle of 83.49 (6)°. The mol­ecular structure features an N—H⋯O hydrogen bond, which generates an S(6) ring motif. The crystal packing is governed by two N—H⋯O inter­actions, one of which generates a centrosymmetric R (2) (2)(14) dimer. The other N—H⋯O inter­action along with a C—H⋯O hydrogen bond contributes to the formation of a C (2) (2)[R (2) (2)(9)] dimeric chain running along the b-axis direction. International Union of Crystallography 2013-06-08 /pmc/articles/PMC3772486/ /pubmed/24046629 http://dx.doi.org/10.1107/S1600536813014967 Text en © Gangadharan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gangadharan, Rajeswari
Sethusankar, K.
Kiruthika, Selvarangam E.
Perumal, P. T.
Methyl 4-anilino-2′,5-dioxo-1′,2′-di­hydro-5H-spiro­[furan-2,3′-indole]-3-carboxyl­ate
title Methyl 4-anilino-2′,5-dioxo-1′,2′-di­hydro-5H-spiro­[furan-2,3′-indole]-3-carboxyl­ate
title_full Methyl 4-anilino-2′,5-dioxo-1′,2′-di­hydro-5H-spiro­[furan-2,3′-indole]-3-carboxyl­ate
title_fullStr Methyl 4-anilino-2′,5-dioxo-1′,2′-di­hydro-5H-spiro­[furan-2,3′-indole]-3-carboxyl­ate
title_full_unstemmed Methyl 4-anilino-2′,5-dioxo-1′,2′-di­hydro-5H-spiro­[furan-2,3′-indole]-3-carboxyl­ate
title_short Methyl 4-anilino-2′,5-dioxo-1′,2′-di­hydro-5H-spiro­[furan-2,3′-indole]-3-carboxyl­ate
title_sort methyl 4-anilino-2′,5-dioxo-1′,2′-di­hydro-5h-spiro­[furan-2,3′-indole]-3-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772486/
https://www.ncbi.nlm.nih.gov/pubmed/24046629
http://dx.doi.org/10.1107/S1600536813014967
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