Cargando…
Methyl 4-anilino-2′,5-dioxo-1′,2′-dihydro-5H-spiro[furan-2,3′-indole]-3-carboxylate
In the title compound, C(19)H(14)N(2)O(5), the spiro junction links an oxindole moeity and a furan ring, which subtend a dihedral angle of 83.49 (6)°. The molecular structure features an N—H⋯O hydrogen bond, which generates an S(6) ring motif. The crystal packing is governed by two N—H⋯O interacti...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772486/ https://www.ncbi.nlm.nih.gov/pubmed/24046629 http://dx.doi.org/10.1107/S1600536813014967 |
_version_ | 1782284341903097856 |
---|---|
author | Gangadharan, Rajeswari Sethusankar, K. Kiruthika, Selvarangam E. Perumal, P. T. |
author_facet | Gangadharan, Rajeswari Sethusankar, K. Kiruthika, Selvarangam E. Perumal, P. T. |
author_sort | Gangadharan, Rajeswari |
collection | PubMed |
description | In the title compound, C(19)H(14)N(2)O(5), the spiro junction links an oxindole moeity and a furan ring, which subtend a dihedral angle of 83.49 (6)°. The molecular structure features an N—H⋯O hydrogen bond, which generates an S(6) ring motif. The crystal packing is governed by two N—H⋯O interactions, one of which generates a centrosymmetric R (2) (2)(14) dimer. The other N—H⋯O interaction along with a C—H⋯O hydrogen bond contributes to the formation of a C (2) (2)[R (2) (2)(9)] dimeric chain running along the b-axis direction. |
format | Online Article Text |
id | pubmed-3772486 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37724862013-09-17 Methyl 4-anilino-2′,5-dioxo-1′,2′-dihydro-5H-spiro[furan-2,3′-indole]-3-carboxylate Gangadharan, Rajeswari Sethusankar, K. Kiruthika, Selvarangam E. Perumal, P. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(14)N(2)O(5), the spiro junction links an oxindole moeity and a furan ring, which subtend a dihedral angle of 83.49 (6)°. The molecular structure features an N—H⋯O hydrogen bond, which generates an S(6) ring motif. The crystal packing is governed by two N—H⋯O interactions, one of which generates a centrosymmetric R (2) (2)(14) dimer. The other N—H⋯O interaction along with a C—H⋯O hydrogen bond contributes to the formation of a C (2) (2)[R (2) (2)(9)] dimeric chain running along the b-axis direction. International Union of Crystallography 2013-06-08 /pmc/articles/PMC3772486/ /pubmed/24046629 http://dx.doi.org/10.1107/S1600536813014967 Text en © Gangadharan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gangadharan, Rajeswari Sethusankar, K. Kiruthika, Selvarangam E. Perumal, P. T. Methyl 4-anilino-2′,5-dioxo-1′,2′-dihydro-5H-spiro[furan-2,3′-indole]-3-carboxylate |
title | Methyl 4-anilino-2′,5-dioxo-1′,2′-dihydro-5H-spiro[furan-2,3′-indole]-3-carboxylate |
title_full | Methyl 4-anilino-2′,5-dioxo-1′,2′-dihydro-5H-spiro[furan-2,3′-indole]-3-carboxylate |
title_fullStr | Methyl 4-anilino-2′,5-dioxo-1′,2′-dihydro-5H-spiro[furan-2,3′-indole]-3-carboxylate |
title_full_unstemmed | Methyl 4-anilino-2′,5-dioxo-1′,2′-dihydro-5H-spiro[furan-2,3′-indole]-3-carboxylate |
title_short | Methyl 4-anilino-2′,5-dioxo-1′,2′-dihydro-5H-spiro[furan-2,3′-indole]-3-carboxylate |
title_sort | methyl 4-anilino-2′,5-dioxo-1′,2′-dihydro-5h-spiro[furan-2,3′-indole]-3-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772486/ https://www.ncbi.nlm.nih.gov/pubmed/24046629 http://dx.doi.org/10.1107/S1600536813014967 |
work_keys_str_mv | AT gangadharanrajeswari methyl4anilino25dioxo12dihydro5hspirofuran23indole3carboxylate AT sethusankark methyl4anilino25dioxo12dihydro5hspirofuran23indole3carboxylate AT kiruthikaselvarangame methyl4anilino25dioxo12dihydro5hspirofuran23indole3carboxylate AT perumalpt methyl4anilino25dioxo12dihydro5hspirofuran23indole3carboxylate |