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2-[4-(Carbazol-9-yl)phenyl]-1,3-diethyl-1,3-diphenylguanidine
In the title compound, C(35)H(32)N(4), the C—N bond lengths in the guanidine part are 1.286 (3), 1.387 (2) and 1.414 (2) Å, indicating double- and single-bond character. The N—C—N angles are 114.48 (17), 118.78 (17) and 126.72 (17)°, showing a deviation of the CN(3) plane from an ideal trigonal–plan...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772493/ https://www.ncbi.nlm.nih.gov/pubmed/24046636 http://dx.doi.org/10.1107/S1600536813014517 |
Sumario: | In the title compound, C(35)H(32)N(4), the C—N bond lengths in the guanidine part are 1.286 (3), 1.387 (2) and 1.414 (2) Å, indicating double- and single-bond character. The N—C—N angles are 114.48 (17), 118.78 (17) and 126.72 (17)°, showing a deviation of the CN(3) plane from an ideal trigonal–planar geometry. The carbazole ring system is almost planar (r.m.s. deviation = 0.002 Å). In the crystal, molecules are connected by weak C—H⋯N hydrogen bonds, generating a zigzag chain along the ac plane. Weak π–π interactions [centroid–centroid distance = 3.785 (1) Å] between two phenyl rings of the guanidine moiety are also present. |
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