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2-[4-(Carbazol-9-yl)phen­yl]-1,3-diethyl-1,3-di­phenyl­guanidine

In the title compound, C(35)H(32)N(4), the C—N bond lengths in the guanidine part are 1.286 (3), 1.387 (2) and 1.414 (2) Å, indicating double- and single-bond character. The N—C—N angles are 114.48 (17), 118.78 (17) and 126.72 (17)°, showing a deviation of the CN(3) plane from an ideal trigonal–plan...

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Detalles Bibliográficos
Autores principales: Tiritiris, Ioannis, Kantlehner, Willi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772493/
https://www.ncbi.nlm.nih.gov/pubmed/24046636
http://dx.doi.org/10.1107/S1600536813014517
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author Tiritiris, Ioannis
Kantlehner, Willi
author_facet Tiritiris, Ioannis
Kantlehner, Willi
author_sort Tiritiris, Ioannis
collection PubMed
description In the title compound, C(35)H(32)N(4), the C—N bond lengths in the guanidine part are 1.286 (3), 1.387 (2) and 1.414 (2) Å, indicating double- and single-bond character. The N—C—N angles are 114.48 (17), 118.78 (17) and 126.72 (17)°, showing a deviation of the CN(3) plane from an ideal trigonal–planar geometry. The carbazole ring system is almost planar (r.m.s. deviation = 0.002 Å). In the crystal, mol­ecules are connected by weak C—H⋯N hydrogen bonds, generating a zigzag chain along the ac plane. Weak π–π inter­actions [centroid–centroid distance = 3.785 (1) Å] between two phenyl rings of the guanidine moiety are also present.
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spelling pubmed-37724932013-09-17 2-[4-(Carbazol-9-yl)phen­yl]-1,3-diethyl-1,3-di­phenyl­guanidine Tiritiris, Ioannis Kantlehner, Willi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(35)H(32)N(4), the C—N bond lengths in the guanidine part are 1.286 (3), 1.387 (2) and 1.414 (2) Å, indicating double- and single-bond character. The N—C—N angles are 114.48 (17), 118.78 (17) and 126.72 (17)°, showing a deviation of the CN(3) plane from an ideal trigonal–planar geometry. The carbazole ring system is almost planar (r.m.s. deviation = 0.002 Å). In the crystal, mol­ecules are connected by weak C—H⋯N hydrogen bonds, generating a zigzag chain along the ac plane. Weak π–π inter­actions [centroid–centroid distance = 3.785 (1) Å] between two phenyl rings of the guanidine moiety are also present. International Union of Crystallography 2013-06-08 /pmc/articles/PMC3772493/ /pubmed/24046636 http://dx.doi.org/10.1107/S1600536813014517 Text en © Tiritiris and Kantlehner 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tiritiris, Ioannis
Kantlehner, Willi
2-[4-(Carbazol-9-yl)phen­yl]-1,3-diethyl-1,3-di­phenyl­guanidine
title 2-[4-(Carbazol-9-yl)phen­yl]-1,3-diethyl-1,3-di­phenyl­guanidine
title_full 2-[4-(Carbazol-9-yl)phen­yl]-1,3-diethyl-1,3-di­phenyl­guanidine
title_fullStr 2-[4-(Carbazol-9-yl)phen­yl]-1,3-diethyl-1,3-di­phenyl­guanidine
title_full_unstemmed 2-[4-(Carbazol-9-yl)phen­yl]-1,3-diethyl-1,3-di­phenyl­guanidine
title_short 2-[4-(Carbazol-9-yl)phen­yl]-1,3-diethyl-1,3-di­phenyl­guanidine
title_sort 2-[4-(carbazol-9-yl)phen­yl]-1,3-diethyl-1,3-di­phenyl­guanidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772493/
https://www.ncbi.nlm.nih.gov/pubmed/24046636
http://dx.doi.org/10.1107/S1600536813014517
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