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2-[4-(Carbazol-9-yl)phenyl]-1,3-diethyl-1,3-diphenylguanidine
In the title compound, C(35)H(32)N(4), the C—N bond lengths in the guanidine part are 1.286 (3), 1.387 (2) and 1.414 (2) Å, indicating double- and single-bond character. The N—C—N angles are 114.48 (17), 118.78 (17) and 126.72 (17)°, showing a deviation of the CN(3) plane from an ideal trigonal–plan...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772493/ https://www.ncbi.nlm.nih.gov/pubmed/24046636 http://dx.doi.org/10.1107/S1600536813014517 |
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author | Tiritiris, Ioannis Kantlehner, Willi |
author_facet | Tiritiris, Ioannis Kantlehner, Willi |
author_sort | Tiritiris, Ioannis |
collection | PubMed |
description | In the title compound, C(35)H(32)N(4), the C—N bond lengths in the guanidine part are 1.286 (3), 1.387 (2) and 1.414 (2) Å, indicating double- and single-bond character. The N—C—N angles are 114.48 (17), 118.78 (17) and 126.72 (17)°, showing a deviation of the CN(3) plane from an ideal trigonal–planar geometry. The carbazole ring system is almost planar (r.m.s. deviation = 0.002 Å). In the crystal, molecules are connected by weak C—H⋯N hydrogen bonds, generating a zigzag chain along the ac plane. Weak π–π interactions [centroid–centroid distance = 3.785 (1) Å] between two phenyl rings of the guanidine moiety are also present. |
format | Online Article Text |
id | pubmed-3772493 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-37724932013-09-17 2-[4-(Carbazol-9-yl)phenyl]-1,3-diethyl-1,3-diphenylguanidine Tiritiris, Ioannis Kantlehner, Willi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(35)H(32)N(4), the C—N bond lengths in the guanidine part are 1.286 (3), 1.387 (2) and 1.414 (2) Å, indicating double- and single-bond character. The N—C—N angles are 114.48 (17), 118.78 (17) and 126.72 (17)°, showing a deviation of the CN(3) plane from an ideal trigonal–planar geometry. The carbazole ring system is almost planar (r.m.s. deviation = 0.002 Å). In the crystal, molecules are connected by weak C—H⋯N hydrogen bonds, generating a zigzag chain along the ac plane. Weak π–π interactions [centroid–centroid distance = 3.785 (1) Å] between two phenyl rings of the guanidine moiety are also present. International Union of Crystallography 2013-06-08 /pmc/articles/PMC3772493/ /pubmed/24046636 http://dx.doi.org/10.1107/S1600536813014517 Text en © Tiritiris and Kantlehner 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tiritiris, Ioannis Kantlehner, Willi 2-[4-(Carbazol-9-yl)phenyl]-1,3-diethyl-1,3-diphenylguanidine |
title | 2-[4-(Carbazol-9-yl)phenyl]-1,3-diethyl-1,3-diphenylguanidine |
title_full | 2-[4-(Carbazol-9-yl)phenyl]-1,3-diethyl-1,3-diphenylguanidine |
title_fullStr | 2-[4-(Carbazol-9-yl)phenyl]-1,3-diethyl-1,3-diphenylguanidine |
title_full_unstemmed | 2-[4-(Carbazol-9-yl)phenyl]-1,3-diethyl-1,3-diphenylguanidine |
title_short | 2-[4-(Carbazol-9-yl)phenyl]-1,3-diethyl-1,3-diphenylguanidine |
title_sort | 2-[4-(carbazol-9-yl)phenyl]-1,3-diethyl-1,3-diphenylguanidine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772493/ https://www.ncbi.nlm.nih.gov/pubmed/24046636 http://dx.doi.org/10.1107/S1600536813014517 |
work_keys_str_mv | AT tiritirisioannis 24carbazol9ylphenyl13diethyl13diphenylguanidine AT kantlehnerwilli 24carbazol9ylphenyl13diethyl13diphenylguanidine |