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The preparation of several 1,2,3,4,5-functionalized cyclopentane derivatives

With the goal of eventually synthesizing [5]radialene (3), the still missing member of the parent radialene hydrocarbons, we have prepared the pentaacetates 21 and 31, the pentabromide 29 and the hexabromide 32. In principle these should be convertible by elimination reactions to the desired target...

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Detalles Bibliográficos
Autores principales: Kelch, André S, Jones, Peter G, Dix, Ina, Hopf, Henning
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3778403/
https://www.ncbi.nlm.nih.gov/pubmed/24062831
http://dx.doi.org/10.3762/bjoc.9.195
Descripción
Sumario:With the goal of eventually synthesizing [5]radialene (3), the still missing member of the parent radialene hydrocarbons, we have prepared the pentaacetates 21 and 31, the pentabromide 29 and the hexabromide 32. In principle these should be convertible by elimination reactions to the desired target molecule.