The preparation of several 1,2,3,4,5-functionalized cyclopentane derivatives

With the goal of eventually synthesizing [5]radialene (3), the still missing member of the parent radialene hydrocarbons, we have prepared the pentaacetates 21 and 31, the pentabromide 29 and the hexabromide 32. In principle these should be convertible by elimination reactions to the desired target...

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Detalles Bibliográficos
Autores principales: Kelch, André S, Jones, Peter G, Dix, Ina, Hopf, Henning
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3778403/
https://www.ncbi.nlm.nih.gov/pubmed/24062831
http://dx.doi.org/10.3762/bjoc.9.195
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author Kelch, André S
Jones, Peter G
Dix, Ina
Hopf, Henning
author_facet Kelch, André S
Jones, Peter G
Dix, Ina
Hopf, Henning
author_sort Kelch, André S
collection PubMed
description With the goal of eventually synthesizing [5]radialene (3), the still missing member of the parent radialene hydrocarbons, we have prepared the pentaacetates 21 and 31, the pentabromide 29 and the hexabromide 32. In principle these should be convertible by elimination reactions to the desired target molecule.
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spelling pubmed-37784032013-09-23 The preparation of several 1,2,3,4,5-functionalized cyclopentane derivatives Kelch, André S Jones, Peter G Dix, Ina Hopf, Henning Beilstein J Org Chem Full Research Paper With the goal of eventually synthesizing [5]radialene (3), the still missing member of the parent radialene hydrocarbons, we have prepared the pentaacetates 21 and 31, the pentabromide 29 and the hexabromide 32. In principle these should be convertible by elimination reactions to the desired target molecule. Beilstein-Institut 2013-08-19 /pmc/articles/PMC3778403/ /pubmed/24062831 http://dx.doi.org/10.3762/bjoc.9.195 Text en Copyright © 2013, Kelch et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Kelch, André S
Jones, Peter G
Dix, Ina
Hopf, Henning
The preparation of several 1,2,3,4,5-functionalized cyclopentane derivatives
title The preparation of several 1,2,3,4,5-functionalized cyclopentane derivatives
title_full The preparation of several 1,2,3,4,5-functionalized cyclopentane derivatives
title_fullStr The preparation of several 1,2,3,4,5-functionalized cyclopentane derivatives
title_full_unstemmed The preparation of several 1,2,3,4,5-functionalized cyclopentane derivatives
title_short The preparation of several 1,2,3,4,5-functionalized cyclopentane derivatives
title_sort preparation of several 1,2,3,4,5-functionalized cyclopentane derivatives
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3778403/
https://www.ncbi.nlm.nih.gov/pubmed/24062831
http://dx.doi.org/10.3762/bjoc.9.195
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