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Gold(I)-catalyzed formation of furans from γ-acyloxyalkynyl ketones

Various γ-acyloxyalkynyl ketones were efficiently converted into highly substituted furans with 2.5 mol % of triflimide (triphenylphosphine)gold(I) as a catalyst in dichloroethane at 70 °C.

Detalles Bibliográficos
Autores principales: Hoffmann, Marie, Miaskiewicz, Solène, Weibel, Jean-Marc, Pale, Patrick, Blanc, Aurélien
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3778415/
https://www.ncbi.nlm.nih.gov/pubmed/24062842
http://dx.doi.org/10.3762/bjoc.9.206
Descripción
Sumario:Various γ-acyloxyalkynyl ketones were efficiently converted into highly substituted furans with 2.5 mol % of triflimide (triphenylphosphine)gold(I) as a catalyst in dichloroethane at 70 °C.