Bis[μ-1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hydrazine]bis­[(nitrato-κO)silver(I)] aceto­nitrile disolvate

In the centrosymmetric binuclear title complex, [Ag(2)(NO(3))(2)(C(11)H(8)Cl(2)N(4))(2)]·2CH(3)CN, the Ag(I) atom is four-coordinated and exhibits a highly distorted tetrahedral coordination sphere defined by three N atoms from two 1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hy­drazi...

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Detalles Bibliográficos
Autores principales: Guo, Ying, Cai, Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790340/
https://www.ncbi.nlm.nih.gov/pubmed/24098162
http://dx.doi.org/10.1107/S1600536813024021
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author Guo, Ying
Cai, Hua
author_facet Guo, Ying
Cai, Hua
author_sort Guo, Ying
collection PubMed
description In the centrosymmetric binuclear title complex, [Ag(2)(NO(3))(2)(C(11)H(8)Cl(2)N(4))(2)]·2CH(3)CN, the Ag(I) atom is four-coordinated and exhibits a highly distorted tetrahedral coordination sphere defined by three N atoms from two 1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hy­drazine ligands and one O atom from a nitrate anion. Inter­molecular N—H⋯O hydrogen bonds link the complex mol­ecules, resulting in a two-dimensional supra­molecular structure parallel to (001).
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spelling pubmed-37903402013-10-04 Bis[μ-1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hydrazine]bis­[(nitrato-κO)silver(I)] aceto­nitrile disolvate Guo, Ying Cai, Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric binuclear title complex, [Ag(2)(NO(3))(2)(C(11)H(8)Cl(2)N(4))(2)]·2CH(3)CN, the Ag(I) atom is four-coordinated and exhibits a highly distorted tetrahedral coordination sphere defined by three N atoms from two 1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hy­drazine ligands and one O atom from a nitrate anion. Inter­molecular N—H⋯O hydrogen bonds link the complex mol­ecules, resulting in a two-dimensional supra­molecular structure parallel to (001). International Union of Crystallography 2013-09-04 /pmc/articles/PMC3790340/ /pubmed/24098162 http://dx.doi.org/10.1107/S1600536813024021 Text en © Guo and Cai 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Ying
Cai, Hua
Bis[μ-1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hydrazine]bis­[(nitrato-κO)silver(I)] aceto­nitrile disolvate
title Bis[μ-1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hydrazine]bis­[(nitrato-κO)silver(I)] aceto­nitrile disolvate
title_full Bis[μ-1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hydrazine]bis­[(nitrato-κO)silver(I)] aceto­nitrile disolvate
title_fullStr Bis[μ-1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hydrazine]bis­[(nitrato-κO)silver(I)] aceto­nitrile disolvate
title_full_unstemmed Bis[μ-1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hydrazine]bis­[(nitrato-κO)silver(I)] aceto­nitrile disolvate
title_short Bis[μ-1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hydrazine]bis­[(nitrato-κO)silver(I)] aceto­nitrile disolvate
title_sort bis[μ-1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hydrazine]bis­[(nitrato-κo)silver(i)] aceto­nitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790340/
https://www.ncbi.nlm.nih.gov/pubmed/24098162
http://dx.doi.org/10.1107/S1600536813024021
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AT caihua bism135dichloropyridin2yl2pyridin3ylmethylidenehydrazinebisnitratokosilveriacetonitriledisolvate

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