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Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2) N (1),N (11))rhenium(I)
In the title compound, [ReCl(C(15)H(16)N(4))(CO)(3)], the Re(I) ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclopentane group is orientated in a transoid fashion with respect to the chloride ligand. The d...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790341/ https://www.ncbi.nlm.nih.gov/pubmed/24098163 http://dx.doi.org/10.1107/S1600536813023076 |
| _version_ | 1782286574143143936 |
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| author | Clegg, Oliver R. Harding, Lindsay P. Miller, John W. Rice, Craig R. |
| author_facet | Clegg, Oliver R. Harding, Lindsay P. Miller, John W. Rice, Craig R. |
| author_sort | Clegg, Oliver R. |
| collection | PubMed |
| description | In the title compound, [ReCl(C(15)H(16)N(4))(CO)(3)], the Re(I) ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclopentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N—H⋯Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (001). |
| format | Online Article Text |
| id | pubmed-3790341 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-37903412013-10-04 Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2) N (1),N (11))rhenium(I) Clegg, Oliver R. Harding, Lindsay P. Miller, John W. Rice, Craig R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ReCl(C(15)H(16)N(4))(CO)(3)], the Re(I) ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclopentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N—H⋯Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (001). International Union of Crystallography 2013-09-04 /pmc/articles/PMC3790341/ /pubmed/24098163 http://dx.doi.org/10.1107/S1600536813023076 Text en © Clegg et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Clegg, Oliver R. Harding, Lindsay P. Miller, John W. Rice, Craig R. Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2) N (1),N (11))rhenium(I) |
| title | Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2)
N
(1),N
(11))rhenium(I) |
| title_full | Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2)
N
(1),N
(11))rhenium(I) |
| title_fullStr | Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2)
N
(1),N
(11))rhenium(I) |
| title_full_unstemmed | Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2)
N
(1),N
(11))rhenium(I) |
| title_short | Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2)
N
(1),N
(11))rhenium(I) |
| title_sort | tricarbonylchlorido(6′,7′-dihydro-5′h-spiro[cyclopentane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2)
n
(1),n
(11))rhenium(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790341/ https://www.ncbi.nlm.nih.gov/pubmed/24098163 http://dx.doi.org/10.1107/S1600536813023076 |
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