Tri­carbonyl­chlorido­(6′,7′-di­hydro-5′H-spiro­[cyclo­hexane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2) N (1),N (11))rhenium(I)

In the title compound, [ReCl(C(16)H(18)N(4))(CO)(3)], the Re(I) ion is coordinated in a distorted octa­hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo­hexane group is orientated in a transoid fashion with respect to the chloride ligand. In the...

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Detalles Bibliográficos
Autores principales: Clegg, Oliver R., Harding, Lindsay P., Miller, John W., Rice, Craig R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790342/
https://www.ncbi.nlm.nih.gov/pubmed/24098164
http://dx.doi.org/10.1107/S1600536813024288
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author Clegg, Oliver R.
Harding, Lindsay P.
Miller, John W.
Rice, Craig R.
author_facet Clegg, Oliver R.
Harding, Lindsay P.
Miller, John W.
Rice, Craig R.
author_sort Clegg, Oliver R.
collection PubMed
description In the title compound, [ReCl(C(16)H(18)N(4))(CO)(3)], the Re(I) ion is coordinated in a distorted octa­hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo­hexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N—H⋯Cl hydrogen bonds link complex mol­ecules, forming a two-dimensional network parallel to (100).
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spelling pubmed-37903422013-10-04 Tri­carbonyl­chlorido­(6′,7′-di­hydro-5′H-spiro­[cyclo­hexane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2) N (1),N (11))rhenium(I) Clegg, Oliver R. Harding, Lindsay P. Miller, John W. Rice, Craig R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ReCl(C(16)H(18)N(4))(CO)(3)], the Re(I) ion is coordinated in a distorted octa­hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo­hexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N—H⋯Cl hydrogen bonds link complex mol­ecules, forming a two-dimensional network parallel to (100). International Union of Crystallography 2013-09-04 /pmc/articles/PMC3790342/ /pubmed/24098164 http://dx.doi.org/10.1107/S1600536813024288 Text en © Clegg et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Clegg, Oliver R.
Harding, Lindsay P.
Miller, John W.
Rice, Craig R.
Tri­carbonyl­chlorido­(6′,7′-di­hydro-5′H-spiro­[cyclo­hexane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2) N (1),N (11))rhenium(I)
title Tri­carbonyl­chlorido­(6′,7′-di­hydro-5′H-spiro­[cyclo­hexane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2) N (1),N (11))rhenium(I)
title_full Tri­carbonyl­chlorido­(6′,7′-di­hydro-5′H-spiro­[cyclo­hexane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2) N (1),N (11))rhenium(I)
title_fullStr Tri­carbonyl­chlorido­(6′,7′-di­hydro-5′H-spiro­[cyclo­hexane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2) N (1),N (11))rhenium(I)
title_full_unstemmed Tri­carbonyl­chlorido­(6′,7′-di­hydro-5′H-spiro­[cyclo­hexane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2) N (1),N (11))rhenium(I)
title_short Tri­carbonyl­chlorido­(6′,7′-di­hydro-5′H-spiro­[cyclo­hexane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2) N (1),N (11))rhenium(I)
title_sort tri­carbonyl­chlorido­(6′,7′-di­hydro-5′h-spiro­[cyclo­hexane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ(2) n (1),n (11))rhenium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790342/
https://www.ncbi.nlm.nih.gov/pubmed/24098164
http://dx.doi.org/10.1107/S1600536813024288
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