{2-[1-(2-Meth­oxy-6-oxidophenyl-κO (6))ethyl­idene]-N-methyl­hydrazinecarbo­thio­amidato-κ(2) N (2),S}(tri­phenyl­phosphane-κP)palladium(II) ethanol monosolvate

In the title compound, [Pd(C(11)H(13)N(3)O(2)S)(C(18)H(15)P)]·C(2)H(5)OH, the Pd(II) atom is tetra­coordinated in a slightly distorted square-planar environment by three donor atoms (NOS) from a thio­semicarbazonate ligand, forming five- and six-membered chelate rings, and a P atom from a neutral tr...

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Autores principales: Anderson, Brian J., O’Rourke, Kelly A., Keeler, Alexander M., Jasinski, Jerry P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790343/
https://www.ncbi.nlm.nih.gov/pubmed/24098165
http://dx.doi.org/10.1107/S1600536813023040
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author Anderson, Brian J.
O’Rourke, Kelly A.
Keeler, Alexander M.
Jasinski, Jerry P.
author_facet Anderson, Brian J.
O’Rourke, Kelly A.
Keeler, Alexander M.
Jasinski, Jerry P.
author_sort Anderson, Brian J.
collection PubMed
description In the title compound, [Pd(C(11)H(13)N(3)O(2)S)(C(18)H(15)P)]·C(2)H(5)OH, the Pd(II) atom is tetra­coordinated in a slightly distorted square-planar environment by three donor atoms (NOS) from a thio­semicarbazonate ligand, forming five- and six-membered chelate rings, and a P atom from a neutral tri­phenyl­phosphane group. The five-membered ring adopts a distorted envelope conformation with Pd(II) as the flap atom, while the six-membered ring forms a slightly twisted screw-boat conformation. A slightly distorted screw-boat form of a meth­oxy­phenyl group is fused to the six-membered ring. Weak C—H⋯O inter­actions form dimers in the asymmetric unit and along [001] which help to stabilize the crystal packing.
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spelling pubmed-37903432013-10-04 {2-[1-(2-Meth­oxy-6-oxidophenyl-κO (6))ethyl­idene]-N-methyl­hydrazinecarbo­thio­amidato-κ(2) N (2),S}(tri­phenyl­phosphane-κP)palladium(II) ethanol monosolvate Anderson, Brian J. O’Rourke, Kelly A. Keeler, Alexander M. Jasinski, Jerry P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(11)H(13)N(3)O(2)S)(C(18)H(15)P)]·C(2)H(5)OH, the Pd(II) atom is tetra­coordinated in a slightly distorted square-planar environment by three donor atoms (NOS) from a thio­semicarbazonate ligand, forming five- and six-membered chelate rings, and a P atom from a neutral tri­phenyl­phosphane group. The five-membered ring adopts a distorted envelope conformation with Pd(II) as the flap atom, while the six-membered ring forms a slightly twisted screw-boat conformation. A slightly distorted screw-boat form of a meth­oxy­phenyl group is fused to the six-membered ring. Weak C—H⋯O inter­actions form dimers in the asymmetric unit and along [001] which help to stabilize the crystal packing. International Union of Crystallography 2013-09-04 /pmc/articles/PMC3790343/ /pubmed/24098165 http://dx.doi.org/10.1107/S1600536813023040 Text en © Anderson et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Anderson, Brian J.
O’Rourke, Kelly A.
Keeler, Alexander M.
Jasinski, Jerry P.
{2-[1-(2-Meth­oxy-6-oxidophenyl-κO (6))ethyl­idene]-N-methyl­hydrazinecarbo­thio­amidato-κ(2) N (2),S}(tri­phenyl­phosphane-κP)palladium(II) ethanol monosolvate
title {2-[1-(2-Meth­oxy-6-oxidophenyl-κO (6))ethyl­idene]-N-methyl­hydrazinecarbo­thio­amidato-κ(2) N (2),S}(tri­phenyl­phosphane-κP)palladium(II) ethanol monosolvate
title_full {2-[1-(2-Meth­oxy-6-oxidophenyl-κO (6))ethyl­idene]-N-methyl­hydrazinecarbo­thio­amidato-κ(2) N (2),S}(tri­phenyl­phosphane-κP)palladium(II) ethanol monosolvate
title_fullStr {2-[1-(2-Meth­oxy-6-oxidophenyl-κO (6))ethyl­idene]-N-methyl­hydrazinecarbo­thio­amidato-κ(2) N (2),S}(tri­phenyl­phosphane-κP)palladium(II) ethanol monosolvate
title_full_unstemmed {2-[1-(2-Meth­oxy-6-oxidophenyl-κO (6))ethyl­idene]-N-methyl­hydrazinecarbo­thio­amidato-κ(2) N (2),S}(tri­phenyl­phosphane-κP)palladium(II) ethanol monosolvate
title_short {2-[1-(2-Meth­oxy-6-oxidophenyl-κO (6))ethyl­idene]-N-methyl­hydrazinecarbo­thio­amidato-κ(2) N (2),S}(tri­phenyl­phosphane-κP)palladium(II) ethanol monosolvate
title_sort {2-[1-(2-meth­oxy-6-oxidophenyl-κo (6))ethyl­idene]-n-methyl­hydrazinecarbo­thio­amidato-κ(2) n (2),s}(tri­phenyl­phosphane-κp)palladium(ii) ethanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790343/
https://www.ncbi.nlm.nih.gov/pubmed/24098165
http://dx.doi.org/10.1107/S1600536813023040
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